Hoy Robert S
Department of Physics, University of South Florida, 33620, Tampa, FL, USA.
Eur Phys J E Soft Matter. 2019 Jan 9;42(1):2. doi: 10.1140/epje/i2019-11763-5.
We discuss issues related to thermalization of plastic flow in the context of soft glassy rheology (SGR) theory. An apparent problem with the theory in its current form is that the stationarity of thermomechanical equilibrium obtained by requiring that its flow rule satisfy detailed balance in the absence of applied deformation requires plastic flow to be athermal. This prevents proper application of SGR to small-molecule and polymer glasses where plastic flow is often well thermalized. Clearly, one would like to have a SGR-like theory of thermalized plastic flow that satisfies stationarity. We discuss reasons why such a theory could prove very useful and clarify obstacles that must be overcome in order to develop it.
我们在软玻璃态流变学(SGR)理论的背景下讨论与塑性流动热化相关的问题。该理论当前形式存在的一个明显问题是,在没有施加变形的情况下,通过要求其流动规则满足细致平衡来获得热机械平衡的平稳性,这要求塑性流动是无热的。这使得SGR无法适当地应用于小分子和聚合物玻璃,因为在这些材料中塑性流动通常是充分热化的。显然,人们希望有一个类似SGR的热化塑性流动理论,该理论能满足平稳性。我们讨论了这样一个理论可能非常有用的原因,并阐明了开发该理论必须克服的障碍。