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同形物、隐藏的尺度不变性和准普遍性。

Isomorphs, hidden scale invariance, and quasiuniversality.

作者信息

Dyre Jeppe C

机构信息

DNRF Center "Glass and Time,"IMFUFA, Dept. of Sciences, Roskilde University, P. O. Box 260, DK-4000 Roskilde, Denmark.

出版信息

Phys Rev E Stat Nonlin Soft Matter Phys. 2013 Oct;88(4):042139. doi: 10.1103/PhysRevE.88.042139. Epub 2013 Oct 24.

Abstract

This paper first establishes an approximate scaling property of the potential-energy function of a classical liquid with good isomorphs (a Roskilde-simple liquid). This "pseudohomogeneous" property makes explicit that-and in which sense-such a system has a hidden scale invariance. The second part of the paper gives a potential-energy formulation of the quasiuniversality of monatomic Roskilde-simple liquids, which was recently rationalized in terms of the existence of a quasiuniversal single-parameter family of reduced-coordinate constant-potential-energy hypersurfaces [J. C. Dyre, Phys. Rev. E 87, 022106 (2013)]. The new formulation involves a quasiuniversal reduced-coordinate potential-energy function. A few consequences of this are discussed.

摘要

本文首先建立了具有良好同构体(罗斯基勒简单液体)的经典液体势能函数的近似标度性质。这种“准均匀”性质明确了——以及在何种意义上——这样一个系统具有隐藏的标度不变性。本文的第二部分给出了单原子罗斯基勒简单液体准普适性的势能表述,最近根据简化坐标等势能超曲面的准普适单参数族的存在对其进行了合理化解释[J. C. 戴尔,《物理评论E》87, 022106 (2013)]。新的表述涉及一个准普适的简化坐标势能函数。讨论了由此产生的一些结果。

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