Saxton W L
J Chromatogr. 1986 Apr 23;357(1):1-10. doi: 10.1016/s0021-9673(01)95803-0.
Tables of relative retention times, retention indices or emergence temperatures obtained under one set of chromatographic conditions can be used for the tentative identification of unknowns determined under an entirely different set of conditions. This can be accomplished for a particular liquid phase if the emergence temperature of a reference compound is maintained while one or more chromatographic parameters are changed to compensate for the changes in other parameters. The advantage of using proximal standards for the determination of both relative retention times and emergence temperatures is demonstrated in this report.
在一组色谱条件下获得的相对保留时间、保留指数或流出温度表，可用于初步鉴定在完全不同的另一组条件下测定的未知物。如果在改变一个或多个色谱参数以补偿其他参数变化的同时，保持参考化合物的流出温度不变，那么对于特定的固定液就可以实现这一点。本报告展示了使用近端标准物来测定相对保留时间和流出温度的优势。
