Saxton W L
J Chromatogr. 1987 Apr 29;393(2):175-94. doi: 10.1016/s0021-9673(01)94217-7.
Emergence temperature indices and relative retention times of nearly 600 pesticides and industrial chemicals are sequentially tabulated to provide a basis for the identification of unknowns detected on methyl silicone columns when programmed temperature gas chromatography is used. A technique of normalizing column parameters is described to enable duplication of the tabulated data on columns which have different dimensions, amount of stationary phase, and/or other operating parameters. Suggestions for enhancing the precision with which these data can be reproduced on other equipment are presented.
将近600种农药和工业化学品的出峰温度指数及相对保留时间依次制成表格，以便在使用程序升温气相色谱法时，为鉴定甲基硅氧烷柱上检测到的未知物提供依据。文中描述了一种使柱参数归一化的技术，以便在具有不同尺寸、固定相含量和/或其他操作参数的色谱柱上重复表格中的数据。还给出了提高在其他设备上重现这些数据精度的建议。
