氟化对高效光伏聚合物分子能级调节的协同效应。
Synergistic effect of fluorination on molecular energy level modulation in highly efficient photovoltaic polymers.
机构信息
State Key Laboratory of Polymer Physics and Chemistry, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190, China.
出版信息
Adv Mater. 2014 Feb;26(7):1118-23. doi: 10.1002/adma.201304427. Epub 2013 Nov 20.
PMID:24259399
Abstract
The synergistic effect of fluorination on molecular energy level modulation is realized by introducing fluorine atoms onto both the donor and the acceptor moieties in a D-A polymer, and as a result, the polymer solar cell device based on the trifluorinated polymer, PBT-3F, shows a high efficiency of 8.6%, under illumination of AM 1.5G, 100 mW cm(-) (2) .
摘要
通过在 D-A 聚合物的给体和受体部分都引入氟原子，实现了氟化对分子能级调节的协同效应，因此，基于三氟聚合物 PBT-3F 的聚合物太阳能电池器件在 AM 1.5G、100 mW cm(-2) 的光照下表现出 8.6%的高效率。
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