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基于聚合物/PbSxSe1-x 纳米晶的高效混合太阳能电池,得益于垂直相分离。

High-efficiency hybrid solar cells based on polymer/PbSx Se1-x nanocrystals benefiting from vertical phase segregation.

机构信息

Institute of Functional Nano & Soft Materials (FUNSOM) Soochow University, 199 Ren-Ai Road, Suzhou Industrial Park, Suzhou, Jiangsu, 215123, China.

出版信息

Adv Mater. 2013 Oct 25;25(40):5772-8. doi: 10.1002/adma.201302340. Epub 2013 Aug 12.

DOI:10.1002/adma.201302340
PMID:23934968
Abstract

Solution-processed hybrid solar cells employing a low band-gap polymer and PbSx Se1-x alloy nanocrystals, achieving a record high PCE of 5.50% and an optimal FF of 67% are presented. The remarkable device efficiency can be attributed to the high-performance active materials, the optimal polymer/NCs ratio and, more importantly, the vertical donor/(donor:acceptor)/acceptor structure which benefits charge dissociation and transport.

摘要

采用低带隙聚合物和 PbSx Se1-x 合金纳米晶的溶液处理混合太阳能电池,实现了创纪录的高 PCE(光电转换效率)5.50%和最佳 FF(填充因子)67%。显著的器件效率可归因于高性能的活性材料、最佳的聚合物/NCs 比例,更重要的是,垂直施主/(施主:受体)/受体结构有利于电荷的解离和传输。

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