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采用固相微萃取-气相色谱/质谱法检测部分中式食品中的呋喃水平及中国人膳食呋喃暴露评估。

Detection of furan levels in select Chinese foods by solid phase microextraction-gas chromatography/mass spectrometry method and dietary exposure estimation of furan in the Chinese population.

机构信息

College of Quartermaster Technology, Jilin University, Changchun 130062, China.

College of Quartermaster Technology, Jilin University, Changchun 130062, China.

出版信息

Food Chem Toxicol. 2014 Feb;64:34-40. doi: 10.1016/j.fct.2013.11.012. Epub 2013 Nov 19.

Abstract

In this study, a solid phase microextraction-gas chromatography/mass spectrometry (SPMEGC/MS) method was developed to detection the levels of furan in 191 selected food products obtained from the Chinese markets. The performance of the analysis method was evaluated by some quality parameters such as limit of detection (LOD), limit of quantification (LOQ), linearity, recovery, and runto-run (n=6) and day-to-day (n=18) precisions. The LOD and the LOQ of the method were 0.059 ng/g and 0.175 ng/g, respectively. The recovery of the method in fruit juice, canned jam, and infant formula ranged from 93.25% to 104.69%. The results from this study showed that furan was detected in almost all analyzed samples. Furan contents in different food samples varied greatly according to the raw materials and processing conditions. The higher contents of furan were detected in traditional Chinese liquor (61.63 ng/g), coffee (71.36 ng/g), tea (68.28 ng/g) and pickle (85.63 ng/g). The dietary intake of furan was estimated to be 0.093 μg/kg b.w.t/day in adults and 0.333 μg/kg b.w.t/day in infants at 6 months. Further studies are needed to reveal other sources of dietary furan exposure.

摘要

本研究建立了一种固相微萃取-气相色谱/质谱联用(SPME-GC/MS)方法,用于检测从中国市场购买的 191 种食品中呋喃的含量。通过一些质量参数,如检测限(LOD)、定量限(LOQ)、线性、回收率以及日内(n=6)和日间(n=18)精密度来评估分析方法的性能。该方法的 LOD 和 LOQ 分别为 0.059ng/g 和 0.175ng/g。果汁、果酱罐头和婴儿配方食品中该方法的回收率在 93.25%至 104.69%之间。本研究结果表明,几乎所有分析的样品中都检测到了呋喃。不同食品样品中的呋喃含量根据原料和加工条件的不同而有很大差异。传统中国白酒(61.63ng/g)、咖啡(71.36ng/g)、茶(68.28ng/g)和泡菜(85.63ng/g)中的呋喃含量较高。成年人通过饮食摄入的呋喃估计为 0.093μg/kg bw.t/day,6 个月大的婴儿为 0.333μg/kg bw.t/day。需要进一步的研究来揭示其他饮食中呋喃暴露的来源。

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