Pal S, Zavalij P Y, Vedernikov A N
Department of Chemistry and Biochemistry, University of Maryland, College Park, MD 20742, USA.
Chem Commun (Camb). 2014 May 25;50(40):5376-8. doi: 10.1039/c3cc47445c. Epub 2013 Nov 28.
Dimethyl- and diphenylplatinum(II) fragments Pt(II)R2 (R = Me, Ph) enable facile and efficient oxidative C(sp(3))-H bond cleavage and stepwise C-C and C=C coupling at the boron atom of a coordinated 1,5-cyclooctanediyldi(2-pyridyl)borato ligand with O2 as the sole oxidant.
二甲基和二苯基铂（II）片段Pt（II）R2（R = 甲基、苯基）能够以O2作为唯一氧化剂，在配位的1,5-环辛二烯二（2-吡啶基）硼酸酯配体的硼原子上轻松高效地实现氧化C（sp(3)）-H键裂解以及逐步的C-C和C=C偶联。
