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利用香蕉皮作为新型生物吸附剂处理和脱色生物处理后的棕榈油厂废水(POME)。

Treatment and decolorization of biologically treated Palm Oil Mill Effluent (POME) using banana peel as novel biosorbent.

机构信息

Department of Chemical and Environmental Engineering, Faculty of Engineering, University of Nottingham Malaysia campus, 43500 Semenyih, Selangor, Malaysia; Department of Chemical Industries, Mosul Technical Institute, Al-Majmoa'a Al-Thaqafiya, Mosul, Iraq.

Department of Chemical and Environmental Engineering, Faculty of Engineering, University of Nottingham Malaysia campus, 43500 Semenyih, Selangor, Malaysia.

出版信息

J Environ Manage. 2014 Jan;132:237-49. doi: 10.1016/j.jenvman.2013.11.031. Epub 2013 Dec 8.

Abstract

Palm Oil Mill Effluent (POME) treatment has always been a topic of research in Malaysia. This effluent that is extremely rich in organic content needs to be properly treated to minimize environmental hazards before it is released into watercourses. The main aim of this work is to evaluate the potential of applying natural, chemically and thermally modified banana peel as sorbent for the treatment of biologically treated POME. Characteristics of these sorbents were analyzed with BET surface area and SEM. Batch adsorption studies were carried out to remove color, total suspended solids (TSS), chemical oxygen demand (COD), tannin and lignin, and biological oxygen demand (BOD) onto natural banana peel (NBP), methylated banana peel (MBP), and banana peel activated carbon (BPAC) respectively. The variables of pH, adsorbent dosage, and contact time were investigated in this study. Maximum percentage removal of color, TSS, COD, BOD, and tannin and lignin (95.96%, 100%, 100%, 97.41%, and 76.74% respectively) on BPAC were obtained at optimized pH of 2, contact time of 30 h and adsorbent dosage of 30 g/100 ml. The isotherm data were well described by the Redlich-Peterson isotherm model with correlation coefficient of more than 0.99. Kinetic of adsorption was examined by Langergren pseudo first order, pseudo second order, and second order. The pseudo second order was identified to be the governing mechanism with high correlation coefficient of more than 0.99.

摘要

棕榈油厂废水(POME)处理一直是马来西亚的研究课题。这种富含有机物的废水需要经过适当处理,以最大限度地减少对水系统的环境危害,然后才能排放到水道中。这项工作的主要目的是评估天然、化学和热改性香蕉皮作为吸附剂处理经生物处理的 POME 的潜力。通过 BET 表面积和 SEM 分析了这些吸附剂的特性。进行了批量吸附研究,以天然香蕉皮(NBP)、甲基化香蕉皮(MBP)和香蕉皮活性炭(BPAC)分别去除颜色、总悬浮固体(TSS)、化学需氧量(COD)、单宁和木质素以及生物需氧量(BOD)。本研究考察了 pH、吸附剂用量和接触时间等变量。在优化的 pH 值为 2、接触时间为 30 h 和吸附剂用量为 30 g/100 ml 条件下,BPAC 对颜色、TSS、COD、BOD 和单宁和木质素的去除率最高(分别为 95.96%、100%、100%、97.41%和 76.74%)。等温线数据通过 Redlich-Peterson 等温模型得到了很好的描述,相关系数均大于 0.99。通过 Langergren 拟一级、拟二级和二级动力学模型研究了吸附动力学。拟二级动力学被确定为主要的控制机制,相关系数均大于 0.99。

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