二氟卡宾逐步加成到过渡金属中心。
Stepwise addition of difluorocarbene to a transition metal centre.
作者信息
Lee Graham M, Harrison Daniel J, Korobkov Ilia, Baker R Tom
机构信息
Department of Chemistry and Centre for Catalysis Research and Innovation, University of Ottawa, 30 Marie Curie, Ottawa, Ontario K1N 6N5, Canada.
出版信息
Chem Commun (Camb). 2014 Feb 4;50(9):1128-30. doi: 10.1039/c3cc48468h.
PMID:24322965
Abstract
The Ruppert-Prakash reagent (Me3SiCF3) is used to introduce difluorocarbene (CF2) and tetrafluoroethylene (TFE) ligands to cobalt(I) metal centres, whereby the TFE ligand is generated via [2+1] cycloaddition between [Co]=CF2 and CF2.
摘要
鲁珀特-普拉卡什试剂（Me3SiCF3）用于将二氟卡宾（CF2）和四氟乙烯（TFE）配体引入钴（I）金属中心，其中TFE配体是通过[Co]=CF2与CF2之间的[2+1]环加成反应生成的。
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