• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利:CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法,用中文像聊天一样搜索,搜遍4000万医学文献。AI智能推荐,让科研检索更轻松。

立即免费搜索

文件翻译

保留排版,准确专业,支持PDF/Word/PPT等文件格式,支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述,25分钟生成高质量综述,智能提取关键信息,辅助科研写作。

立即免费体验

通过在空气/水界面上的光化学蒽二聚反应合成共价单层片,并通过 AFM 压痕法对其进行机械特性表征。

Synthesis of a covalent monolayer sheet by photochemical anthracene dimerization at the air/water interface and its mechanical characterization by AFM indentation.

机构信息

Department of Materials, Polymer Chemistry Group, Swiss Federal Institute of Technology, ETH Zürich, HCI J 541, 8093, Zürich, Switzerland.

出版信息

Adv Mater. 2014 Apr 2;26(13):2052-8. doi: 10.1002/adma.201304705. Epub 2013 Dec 17.

DOI:10.1002/adma.201304705
PMID:24347495
Abstract

Covalent monolayer sheets in 2 hours: spreading of threefold anthracene-equipped shape-persistent and amphiphilic monomers at the air/water interface followed by a short photochemical treatment provides access to infinitely sized, strictly monolayered, covalent sheets with in-plane elastic modulus in the range of 19 N/m.

摘要

两小时内形成共价单层片

在空气/水界面上铺展三倍蒽装备的形状保持和两亲单体,然后进行短暂的光化学处理,可获得无限大尺寸、严格单层、具有 19 N/m 范围内面内弹性模量的共价单层片。

相似文献

1
Synthesis of a covalent monolayer sheet by photochemical anthracene dimerization at the air/water interface and its mechanical characterization by AFM indentation.通过在空气/水界面上的光化学蒽二聚反应合成共价单层片,并通过 AFM 压痕法对其进行机械特性表征。
Adv Mater. 2014 Apr 2;26(13):2052-8. doi: 10.1002/adma.201304705. Epub 2013 Dec 17.
2
Approaching two-dimensional copolymers: photoirradiation of anthracene- and diaza-anthracene-bearing monomers in Langmuir monolayers.迈向二维共聚物:在Langmuir单分子层中对含蒽和二氮蒽的单体进行光辐照
Macromol Rapid Commun. 2015 Jan;36(2):151-8. doi: 10.1002/marc.201400569. Epub 2014 Dec 5.
3
Approaching two-dimensional polymers with macroscopic sizes.制备宏观尺寸的二维聚合物。
Chimia (Aarau). 2013;67(4):283-5. doi: 10.2533/chimia.2013.283.
4
Photochemical Creation of Covalent Organic 2D Monolayer Objects in Defined Shapes via a Lithographic 2D Polymerization.通过光刻二维聚合以特定形状光化学创建共价有机二维单层物体。
ACS Nano. 2018 Nov 27;12(11):11294-11306. doi: 10.1021/acsnano.8b05964. Epub 2018 Oct 24.
5
Room Temperature Synthesis of a Covalent Monolayer Sheet at Air/Water Interface Using a Shape-Persistent Photoreactive Amphiphilic Monomer.使用形状持久性光反应性两亲单体在空气/水界面室温合成共价单层片材。
ACS Macro Lett. 2014 Feb 18;3(2):153-158. doi: 10.1021/mz400597k. Epub 2014 Jan 15.
6
Synthesis of compounds presenting three and four anthracene units as potential connectors to mediate infinite lateral growth at the air/water interface.合成具有三个和四个蒽单元的化合物,作为潜在的连接体,以介导在空气/水界面的无限横向生长。
Chemistry. 2008;14(34):10797-807. doi: 10.1002/chem.200800478.
7
Square-micrometer-sized, free-standing organometallic sheets and their square-centimeter-sized multilayers on solid substrates.边长为几毫米的独立有机金属薄片及其在固体基底上的正方形平方厘米多层结构。
Macromol Rapid Commun. 2013 Nov;34(21):1670-80. doi: 10.1002/marc.201300624. Epub 2013 Sep 23.
8
Hysteresis and its impact on characterization of mechanical properties of suspended monolayer molybdenum-disulfide sheets.滞后及其对悬浮单层二硫化钼片机械性能表征的影响。
Phys Chem Chem Phys. 2019 Apr 3;21(14):7454-7461. doi: 10.1039/c8cp07158f.
9
Structural Characterization of a Covalent Monolayer Sheet Obtained by Two-Dimensional Polymerization at an Air/Water Interface.通过在气/水界面二维聚合获得的共价单层片的结构表征。
Angew Chem Int Ed Engl. 2017 Nov 27;56(48):15262-15266. doi: 10.1002/anie.201707140. Epub 2017 Nov 2.
10
Minimally invasive characterization of covalent monolayer sheets using tip-enhanced Raman spectroscopy.采用针尖增强拉曼光谱技术对共价单层片进行微创特征分析。
ACS Nano. 2015 Apr 28;9(4):4252-9. doi: 10.1021/acsnano.5b00629. Epub 2015 Mar 31.

引用本文的文献

1
Hierarchical single-crystal-to-single-crystal transformations of a monomer to a 1D-polymer and then to a 2D-polymer.单体到一维聚合物再到二维聚合物的分级单晶到单晶转变。
Nat Commun. 2024 Aug 5;15(1):6638. doi: 10.1038/s41467-024-51051-z.
2
Ultrathin organic membranes: Can they sustain the quest for mechanically robust device applications?超薄有机膜:它们能否满足对机械坚固的器件应用的追求?
iScience. 2023 Jan 5;26(2):105924. doi: 10.1016/j.isci.2023.105924. eCollection 2023 Feb 17.
3
Interfacial Synthesis of an Ultrathin Two-Dimensional Polymer Film via [2 + 2] Photocycloaddition.
通过[2+2]光环加成反应在界面上合成超薄二维聚合物薄膜。
Molecules. 2023 Feb 17;28(4):1930. doi: 10.3390/molecules28041930.
4
Nanomechanical behavior and interfacial deformation beyond the elastic limit in 2D metal-organic framework nanosheets.二维金属有机框架纳米片中超出弹性极限的纳米力学行为及界面变形
Nanoscale Adv. 2020 Aug 12;2(11):5181-5191. doi: 10.1039/d0na00475h. eCollection 2020 Nov 11.
5
In-situ nanospectroscopic imaging of plasmon-induced two-dimensional [4+4]-cycloaddition polymerization on Au(111).金(111)表面等离激元诱导的二维[4+4]环加成聚合的原位纳米光谱成像
Nat Commun. 2021 Jul 27;12(1):4557. doi: 10.1038/s41467-021-24856-5.
6
Thermo- and light-triggered reversible interconversion of dysprosium-anthracene complexes and their responsive optical, magnetic and dielectric properties.镝-蒽配合物的热触发和光触发可逆互变及其响应性光学、磁性和介电性质。
Chem Sci. 2020 Nov 11;12(3):929-937. doi: 10.1039/d0sc04851h.
7
Room temperature crystallization of amorphous polysiloxane using photodimerization.利用光二聚作用实现非晶态聚硅氧烷的室温结晶
Chem Sci. 2020 Feb 28;11(11):3081-3088. doi: 10.1039/c9sc06235a.
8
On-surface photopolymerization of two-dimensional polymers ordered on the mesoscale.二维聚合物在中尺度上有序排列的表面光聚合反应。
Nat Chem. 2021 Aug;13(8):730-736. doi: 10.1038/s41557-021-00709-y. Epub 2021 Jun 3.
9
Interfacial Synthesis of a Monolayered Fluorescent Two-Dimensional Polymer through Dynamic Imine Chemistry.通过动态亚胺化学实现单层荧光二维聚合物的界面合成。
ChemistryOpen. 2020 Mar 24;9(3):381-385. doi: 10.1002/open.202000041. eCollection 2020 Mar.
10
Tip-enhanced Raman spectroscopy for structural analysis of two-dimensional covalent monolayers synthesized on water and on Au (111).用于对在水和金(111)上合成的二维共价单分子层进行结构分析的针尖增强拉曼光谱。
Chem Sci. 2019 Sep 24;10(42):9673-9678. doi: 10.1039/c9sc03296g. eCollection 2019 Nov 14.