通过在空气/水界面上的光化学蒽二聚反应合成共价单层片，并通过 AFM 压痕法对其进行机械特性表征。
Synthesis of a covalent monolayer sheet by photochemical anthracene dimerization at the air/water interface and its mechanical characterization by AFM indentation.
机构信息
Department of Materials, Polymer Chemistry Group, Swiss Federal Institute of Technology, ETH Zürich, HCI J 541, 8093, Zürich, Switzerland.
出版信息
Adv Mater. 2014 Apr 2;26(13):2052-8. doi: 10.1002/adma.201304705. Epub 2013 Dec 17.
PMID:24347495
Abstract
Covalent monolayer sheets in 2 hours: spreading of threefold anthracene-equipped shape-persistent and amphiphilic monomers at the air/water interface followed by a short photochemical treatment provides access to infinitely sized, strictly monolayered, covalent sheets with in-plane elastic modulus in the range of 19 N/m.
摘要
两小时内形成共价单层片
在空气/水界面上铺展三倍蒽装备的形状保持和两亲单体，然后进行短暂的光化学处理，可获得无限大尺寸、严格单层、具有 19 N/m 范围内面内弹性模量的共价单层片。
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