Department of Chemistry, Inorganic Chemistry Laboratory, University of Oxford , South Parks Road, Oxford OX1 3QR, United Kingdom.
J Am Chem Soc. 2014 Jan 15;136(2):630-3. doi: 10.1021/ja411624q. Epub 2014 Jan 2.
The development of a technique for following in situ the reactions of solids with alkali metal/ammonia solutions, using time-resolved X-ray diffraction methods, reveals high-temperature superconducting ammonia-rich intercalates of iron selenide which reversibly absorb and desorb ammonia around ambient temperatures.
利用时间分辨 X 射线衍射方法开发了一种原位跟踪固体与碱金属/氨溶液反应的技术，该技术揭示了高温超导富氨铁硒化物插层化合物，其可在环境温度附近可逆地吸收和释放氨。
