• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

具有五个芳环的空间位阻二亚胺配体的微流合成与结构分析。

Micro-flow synthesis and structural analysis of sterically crowded diimine ligands with five aryl rings.

机构信息

Department of Applied Chemistry, Tokyo Institute of Technology, 2-12-1, Ookayama, Meguro-ku, Tokyo, 152-8552, Japan.

Mitsubishi Chemical Croup, Science and Technology Research Center, Inc., 1000 Kamoshida-cho, Aoba-ku, Yokohama 227-8502, Japan.

出版信息

Beilstein J Org Chem. 2013 Nov 1;9:2336-43. doi: 10.3762/bjoc.9.268. eCollection 2013.

DOI:10.3762/bjoc.9.268
PMID:24367397
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3869212/
Abstract

Sterically crowded diimine ligands with five aryl rings were prepared in one step in good yields using a micro-flow technique. X-ray crystallographic analysis revealed the detailed structure of the bulky ligands. The nickel complexes prepared from the ligands exerted high polymerization activity in the ethylene homopolymerization and copolymerization of ethylene with polar monomers.

摘要

使用微流技术一步法制备了具有五个芳环的空间位阻拥挤二亚胺配体，产率高。X 射线晶体学分析揭示了配体的详细结构。由配体制备的镍配合物在乙烯均聚和乙烯与极性单体共聚中表现出高聚合活性。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3fc0/3869212/419e21ba64f6/Beilstein_J_Org_Chem-09-2336-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3fc0/3869212/63bc4e9c4ffe/Beilstein_J_Org_Chem-09-2336-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3fc0/3869212/d0660da605a1/Beilstein_J_Org_Chem-09-2336-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3fc0/3869212/c80ec4f63ddc/Beilstein_J_Org_Chem-09-2336-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3fc0/3869212/499c8f1af1af/Beilstein_J_Org_Chem-09-2336-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3fc0/3869212/382c3756750d/Beilstein_J_Org_Chem-09-2336-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3fc0/3869212/4a78c634b679/Beilstein_J_Org_Chem-09-2336-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3fc0/3869212/37a24f616bfe/Beilstein_J_Org_Chem-09-2336-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3fc0/3869212/419e21ba64f6/Beilstein_J_Org_Chem-09-2336-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3fc0/3869212/63bc4e9c4ffe/Beilstein_J_Org_Chem-09-2336-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3fc0/3869212/d0660da605a1/Beilstein_J_Org_Chem-09-2336-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3fc0/3869212/c80ec4f63ddc/Beilstein_J_Org_Chem-09-2336-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3fc0/3869212/499c8f1af1af/Beilstein_J_Org_Chem-09-2336-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3fc0/3869212/382c3756750d/Beilstein_J_Org_Chem-09-2336-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3fc0/3869212/4a78c634b679/Beilstein_J_Org_Chem-09-2336-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3fc0/3869212/37a24f616bfe/Beilstein_J_Org_Chem-09-2336-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3fc0/3869212/419e21ba64f6/Beilstein_J_Org_Chem-09-2336-g006.jpg

相似文献

1
Micro-flow synthesis and structural analysis of sterically crowded diimine ligands with five aryl rings.具有五个芳环的空间位阻二亚胺配体的微流合成与结构分析。
Beilstein J Org Chem. 2013 Nov 1;9:2336-43. doi: 10.3762/bjoc.9.268. eCollection 2013.
2
Nickel-Catalyzed Ethylene Copolymerization with Vinylalkoxysilanes: A Computational Study.镍催化乙烯与乙烯基烷氧基硅烷的共聚反应：一项计算研究。
Polymers (Basel). 2024 Mar 10;16(6):762. doi: 10.3390/polym16060762.
3
Highly Robust Palladium(II) α-Diimine Catalysts for Slow-Chain-Walking Polymerization of Ethylene and Copolymerization with Methyl Acrylate.高度稳定的钯（II）α-二亚胺催化剂用于乙烯的缓慢链增长聚合及与甲基丙烯酸甲酯的共聚反应。
Angew Chem Int Ed Engl. 2015 Aug 17;54(34):9948-53. doi: 10.1002/anie.201503708. Epub 2015 Jun 26.
4
-Functionalized Dibenzhydryl Substituents in -Diimine Pd Catalyzed Ethylene Polymerization and Copolymerization.-二亚胺钯催化乙烯聚合及共聚反应中的官能化二苯甲基取代基
Polymers (Basel). 2020 Oct 28;12(11):2509. doi: 10.3390/polym12112509.
5
Ethylene Polymerizations Catalyzed by Fluorinated "Sandwich" Diimine-Nickel and Palladium Complexes.氟化“夹心”二亚胺镍和钯配合物催化的乙烯聚合反应
J Am Chem Soc. 2024 Jun 5;146(22):15143-15154. doi: 10.1021/jacs.4c01322. Epub 2024 May 23.
6
Exploring Ethylene/Polar Vinyl Monomer Copolymerizations Using Ni and Pd α-Diimine Catalysts.使用镍和钯α-二亚胺催化剂探索乙烯/极性乙烯基单体共聚反应。
Acc Chem Res. 2018 Aug 21;51(8):1831-1839. doi: 10.1021/acs.accounts.8b00225. Epub 2018 Jul 20.
7
Copolymerization of ethylene with polar monomers: chain propagation and side reactions. A DFT theoretical study using zwitterionic Ni(II) and Pd(II) catalysts.乙烯与极性单体的共聚反应：链增长与副反应。使用两性离子镍（II）和钯（II）催化剂的密度泛函理论研究。
J Am Chem Soc. 2005 Oct 26;127(42):14692-703. doi: 10.1021/ja052350x.
8
Ethylene polymerization of nickel catalysts with α-diimine ligands: factors controlling the structure of active species and polymer properties.具有α-二亚胺配体的镍催化剂的乙烯聚合：控制活性物种结构和聚合物性能的因素。
Dalton Trans. 2019 Jun 21;48(23):7974-7984. doi: 10.1039/c9dt01297d. Epub 2019 May 9.
9
α-Diamine Nickel Catalysts with Nonplanar Chelate Rings for Ethylene Polymerization.用于乙烯聚合的具有非平面螯合环的α-二胺镍催化剂。
Chemistry. 2016 Sep 19;22(39):14048-14055. doi: 10.1002/chem.201602467. Epub 2016 Aug 12.
10
Quantification of the steric influence of alkylphosphine-sulfonate ligands on polymerization, leading to high-molecular-weight copolymers of ethylene and polar monomers.定量研究了烷基膦酸酯配体的空间位阻对聚合反应的影响，从而得到了乙烯和极性单体的高分子量共聚物。
J Am Chem Soc. 2014 Aug 27;136(34):11898-901. doi: 10.1021/ja505558e. Epub 2014 Aug 13.

引用本文的文献

1
Total synthesis of feglymycin based on a linear/convergent hybrid approach using micro-flow amide bond formation.基于使用微流酰胺键形成的线性/汇聚混合方法的飞格霉素全合成。
Nat Commun. 2016 Nov 28;7:13491. doi: 10.1038/ncomms13491.
2
Efficient amide bond formation through a rapid and strong activation of carboxylic acids in a microflow reactor.在微流反应器中通过快速而强烈的羧酸活化作用实现高效酰胺键形成。
Angew Chem Int Ed Engl. 2014 Jan 13;53(3):851-5. doi: 10.1002/anie.201307987. Epub 2013 Dec 2.

本文引用的文献

1
One-pot, three-component coupling approach to the synthesis of α-iminocarboxamides.一锅法、三组分偶联法合成α-亚氨基甲酰胺。
Org Lett. 2012 Aug 17;14(16):4090-3. doi: 10.1021/ol3017337. Epub 2012 Aug 3.
2
Continuous-flow synthesis of activated vitamin D3 and its analogues.连续流法合成活性维生素 D3 及其类似物。
Org Biomol Chem. 2012 Jul 21;10(27):5205-11. doi: 10.1039/c2ob25511a. Epub 2012 May 16.
3
Synthesis, reactivity and applications of zinc-zinc bonded complexes.锌-锌键合配合物的合成、反应性及应用。
Chem Soc Rev. 2012 May 21;41(10):3759-71. doi: 10.1039/c2cs15343b. Epub 2012 Mar 1.
4
Continuous in situ generation and reaction of phosgene in a microflow system.微流系统中连续原位生成和反应光气。
Chem Commun (Camb). 2011 Dec 21;47(47):12661-3. doi: 10.1039/c1cc15662d. Epub 2011 Oct 31.
5
Combinatorial synthesis and evaluation of α-iminocarboxamide-nickel(II) catalysts for the copolymerization of ethylene and a polar monomer.α-亚氨基酰胺-镍（II）催化剂的组合合成与评价及其在乙烯与极性单体共聚反应中的应用。
ACS Comb Sci. 2012 Jan 9;14(1):17-24. doi: 10.1021/co200081j. Epub 2011 Nov 15.
6
Green and sustainable chemical synthesis using flow microreactors.使用流动微反应器进行绿色可持续的化学合成。
ChemSusChem. 2011 Mar 21;4(3):331-40. doi: 10.1002/cssc.201000271. Epub 2010 Nov 24.
7
Transmetalation of unsaturated carbon nucleophiles from boron-containing species to the mid to late d-block metals of relevance to catalytic C-X coupling reactions (X = C, F, N, O, Pb, S, Se, Te).不饱和碳亲核试剂从含硼物种到与催化碳-卤（X = C、F、N、O、Pb、S、Se、Te）偶联反应相关的d区中期到后期金属的金属转移反应。
Chem Rev. 2011 Mar 9;111(3):1529-95. doi: 10.1021/cr1002276.
8
Multinuclear olefin polymerization catalysts.多核烯烃聚合催化剂。
Chem Rev. 2011 Mar 9;111(3):2450-85. doi: 10.1021/cr1003634. Epub 2011 Feb 17.
9
N-heterocyclic carbene analogues with low-valent group 13 and group 14 elements: syntheses, structures, and reactivities of a new generation of multitalented ligands.含低价第13族和第14族元素的氮杂环卡宾类似物：新一代多功能配体的合成、结构及反应活性
Chem Rev. 2011 Feb 9;111(2):354-96. doi: 10.1021/cr100216y. Epub 2010 Dec 6.
10
Design of vanadium complex catalysts for precise olefin polymerization.用于精确烯烃聚合的钒配合物催化剂的设计
Chem Rev. 2011 Mar 9;111(3):2342-62. doi: 10.1021/cr100207h. Epub 2010 Oct 29.