社区空气中农药监测。第 3 部分:使用基于健康的筛选水平来评估一年收集的结果。

Community air monitoring for pesticides. Part 3: using health-based screening levels to evaluate results collected for a year.

机构信息

Environmental Monitoring Branch, Department of Pesticide Regulation, CA Environmental Protection Agency, P.O. Box 4015, Sacramento, CA, 95812, USA,

出版信息

Environ Monit Assess. 2014 Mar;186(3):1355-70. doi: 10.1007/s10661-013-3394-x. Epub 2013 Dec 27.

Abstract

The CA Department of Pesticide Regulation (CDPR) and the CA Air Resources Board monitored 40 pesticides, including five degradation products, in Parlier, CA, to determine if its residents were exposed to any of these pesticides and, if so, in what amounts. They included 1,3-dichloropropene, acrolein, arsenic, azinphos-methyl, carbon disulfide, chlorpyrifos and its degradation product, chlorthalonil, copper, cypermethrin, diazinon and its degradation product, dichlorvos, dicofol, dimethoate and its degradation product, diuron, endosulfan and its degradation product, S-ethyl dipropylcarbamothioate (EPTC), formaldehyde, malathion and its degradation product, methyl isothiocyanate (MITC), methyl bromide, metolachlor, molinate, norflurazon, oryzalin, oxyfluorfen, permethrin, phosmet, propanil, propargite, simazine, SSS-tributylphosphorotrithioate, sulfur, thiobencarb, trifluralin, and xylene. Monitoring was conducted 3 days per week for a year. Twenty-three pesticides and degradation products were detected. Acrolein, arsenic, carbon disulfide, chlorpyrifos, copper, formaldehyde, methyl bromide, MITC, and sulfur were detected in more than half the samples. Since no regulatory ambient air standards exist for these pesticides, CDPR developed advisory, health-based non-cancer screening levels (SLs) to assess acute, subchronic, and chronic exposures. For carcinogenic pesticides, CDPR assessed risk using cancer potency values. Amongst non-carcinogenic agricultural use pesticides, only diazinon exceeded its SL. For carcinogens, 1,3-dichloropropene concentrations exceeded its cancer potency value. Based on these findings, CDPR has undertaken a more comprehensive evaluation of 1,3-dichloropropene, diazinon, and the closely related chlorpyrifos that was frequently detected. Four chemicals-acrolein, arsenic, carbon disulfide, and formaldehyde-sometimes used as pesticides were detected, although no pesticidal use was reported in the area during this study. Their presence was most likely due to vehicular or industrial emissions.

摘要

加利福尼亚州农药监管部门(CDPR)和加利福尼亚州空气资源委员会在加利福尼亚州帕利尔监测了 40 种农药,包括 5 种降解产物,以确定其居民是否接触到这些农药中的任何一种,如果接触到,接触的量有多少。这些农药包括 1,3-二氯丙烯、丙烯醛、砷、涕灭威、二硫化碳、毒死蜱及其降解产物、百菌清、铜、氯菊酯、二嗪磷及其降解产物、敌敌畏、三氯杀螨醇、乐果及其降解产物、二噁烷、硫丹及其降解产物 S-乙基二丙基硫代氨基甲酸盐(EPTC)、甲醛、马拉硫磷及其降解产物、甲基异噻唑啉酮(MITC)、甲基溴、甲草胺、禾草灵、氟唑磺隆、唑草酮、氯氟氰菊酯、氯苯嘧啶醇、苯氧羧酸类除草剂、氟乐灵、二甲戊灵、丙溴磷、噻苯隆、三氟氯氰菊酯和二甲苯。监测工作每周进行三天,持续一年。共检测到 23 种农药和降解产物。丙烯醛、砷、二硫化碳、毒死蜱、铜、甲醛、甲基溴、MITC 和硫在一半以上的样本中被检出。由于这些农药没有监管的环境空气标准,CDPR 制定了基于健康的非致癌性筛选水平(SL),以评估急性、亚慢性和慢性暴露。对于致癌性农药,CDPR 使用致癌潜力值评估风险。在非致癌性农业使用的农药中,只有二嗪磷超过了其 SL。对于致癌剂,1,3-二氯丙烯的浓度超过了其致癌潜力值。根据这些发现,CDPR 对经常检出的 1,3-二氯丙烯、二嗪磷和密切相关的毒死蜱进行了更全面的评估。四种化学物质——丙烯醛、砷、二硫化碳和甲醛——虽然在该研究期间没有报告在该地区使用农药,但有时也被用作农药。它们的存在很可能是由于车辆或工业排放造成的。

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