An efficient and economical process for lignin depolymerization in biomass-derived solvent tetrahydrofuran.

The depolymerization of renewable lignin for phenolic monomer, a versatile biochemical and precursor for biofuel, has attracted increasing attention. Here, an efficient base-catalyzed depolymerization process for this natural aromatic polymer is presented with cheap industrial solid alkali MgO and biomass-derived solvent tetrahydrofuran (THF). Results showed that more than 13.2% of phenolic monomers were obtained under 250°C for 15 min, because of the excellent lignin dissolution of THF and its promotion effect on the catalytic activity of MgO. Furthermore, comparison characterization on the raw material, products and residual solid using elemental analysis, FT-IR, TG-DSC, Py-GC-MS and chemo-physical absorption and desorption demonstrated that this base-catalyzed process can inhibit char formation significantly. Whereas, the fact that thermal repolymerization of oligomer on the pore and surface of catalyst resulting in the declination of the catalytic performance is responsible for the residue formation.