Instituto G. Donegani SpA, Centro Ricerche Novara, Via G. Fauser, 4-28100, Novara, Italy.
J Chem Ecol. 1983 Feb;9(2):191-200. doi: 10.1007/BF00988036.
Female tip washings of the European goat moth,Cossus cossus L., were found to contain the following compounds that are structurally similar to known pheromone components of Lepidoptera (%): decyl acetate (1.5), (Z)-5-dodecenol (1), (Z)-5-dodecenyl acetate (66), dodecyl acetate (12), (Z)-5-tetradecenyl acetate (14), tetradecyl acetate (4), and hexadecyl acetate (1.5). The washes contained an average of 125 ng of (Z)-5-dodecenyl acetate per female equivalent. EAG responses to nanogram amounts of the identified products indicated that (Z)-5-dodecenyl acetate was the most potent olfactory stimulant followed by (Z)-5-tetradecenyl acetate and (Z)-5-dodecenol, whereas the saturated acetates caused only weak depolarization. A strong EAG response was also recorded for (Z)-3-decenyl acetate, which was not detected in the female tip washings. Field results showed that (Z)-5-dodecenyl acetate was essential for the attraction of the males and that (Z)-3-decenyl acetate improved the attractiveness of (Z)-5-dodecenyl acetate alone or in combination with (Z)-5-tetradecenyl acetate.
欧洲野蚕蛾雌蛾触角的分泌物中含有以下化合物,它们的结构与鳞翅目昆虫的已知信息素成分相似(%):乙酸癸酯(1.5)、(Z)-5-十二烯醇(1)、(Z)-5-十二烯基乙酸酯(66)、乙酸十二酯(12)、(Z)-5-十四烯基乙酸酯(14)、乙酸十四酯(4)和乙酸十六酯(1.5)。每只雌蛾的分泌物中平均含有 125ng 的(Z)-5-十二烯基乙酸酯。触角电位(EAG)对鉴定产物的纳克级数量的反应表明,(Z)-5-十二烯基乙酸酯是最有效的嗅觉刺激物,其次是(Z)-5-十四烯基乙酸酯和(Z)-5-十二烯醇,而饱和乙酸酯仅引起轻微的去极化。(Z)-3-十一烯基乙酸酯也记录到了强烈的 EAG 反应,但在雌蛾触角分泌物中未检测到。田间试验结果表明,(Z)-5-十二烯基乙酸酯是雄蛾吸引的关键物质,(Z)-3-十一烯基乙酸酯可以提高(Z)-5-十二烯基乙酸酯单独或与(Z)-5-十四烯基乙酸酯结合使用的吸引力。