从钌烯烃复分解催化剂经醇解反应制备(η5-3-苯基茚基)氢化物配合物
From ruthenium olefin metathesis catalyst to (η5-3-phenylindenyl)hydrido complex via alcoholysis.
作者信息
Manzini Simone, Nelson David J, Lebl Tomas, Poater Albert, Cavallo Luigi, Slawin Alexandra M Z, Nolan Steven P
机构信息
EaStCHEM School of Chemistry, University of St Andrews, North Haugh, St Andrews, Fife KY16 9ST, UK.
出版信息
Chem Commun (Camb). 2014 Feb 28;50(17):2205-7. doi: 10.1039/c3cc49481k. Epub 2014 Jan 16.
The synthesis and characterisation of [Ru(H)(η(5)-3-phenylindenyl)((i)Bu-Phoban)2] 4 is reported ((i)Bu-Phoban = 9-isobutyl-9-phosphabicyclo-[3.3.1]-nonane). 4 is obtained via alcoholysis of metathesis pre-catalyst M11, in a process that was previously thought to be limited to analogous complex [RuCl2(PPh3)2(3-phenylindenylidene)] (M10).
报道了[Ru(H)(η(5)-3-苯基茚基)((i)Bu-Phoban)2] 4的合成与表征（(i)Bu-Phoban = 9-异丁基-9-磷杂双环-[3.3.1]-壬烷）。4是通过复分解预催化剂M11的醇解反应得到的，该过程以前被认为仅限于类似的配合物[RuCl2(PPh3)2(3-苯基茚叉)] (M10)。
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