Organocatalytic photoreduction of Zn(II) to zinc metal.
作者信息
Brooks Anthony C, Basore Katherine, Bernhard Stefan
机构信息
Department of Chemistry, Carnegie Mellon University, 4400 Fifth Avenue, Pittsburgh, PA 15213, USA.
出版信息
Chem Commun (Camb). 2014 May 25;50(40):5196-9. doi: 10.1039/c3cc47633b. Epub 2014 Jan 21.
PMID:24445658
Abstract
The photoreduction of Zn(II) to Zn metal catalyzed by 8-hydroxyquinoline derivatives is reported. Structure-activity relationships, ideal reaction conditions, and the reaction kinetics are described and a mechanism involving an in situ formed quinolate complex is portrayed.
摘要
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