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金属有机骨架 MIL-88A 六方微棒作为一种新型光催化剂,用于高效脱色亚甲基蓝染料。

Metal-organic frameworks MIL-88A hexagonal microrods as a new photocatalyst for efficient decolorization of methylene blue dye.

机构信息

Laboratory of Advanced Porous Materials and School of Chemistry and Chemical Engineering, Anhui University, Hefei 230039, China.

出版信息

Dalton Trans. 2014 Mar 7;43(9):3792-8. doi: 10.1039/c3dt52574k.

Abstract

Metal-organic frameworks (MOFs) MIL-88A hexagonal microrods as a new photocatalyst show an active performance for methylene blue (MB) dye decolorization using visible light. MB decolorization over the MIL-88A photocatalyst follows first-order kinetics. The addition of a H2O2 electron acceptor can markedly enhance the photocatalytic MB decoloration performance of MIL-88A. Moreover, MIL-88A showed a very stable activity for MB decoloration after four consecutive usages. Owing to the advantages of the visible light response, low cost and abundance in nature, this active MIL-88A MOF photocatalyst would have great potential for environmental purification.

摘要

金属-有机骨架(MOFs) MIL-88A 六方微棒作为一种新型光催化剂,在可见光照射下对亚甲基蓝(MB)染料的脱色表现出活性。MIL-88A 光催化剂上的 MB 脱色符合一级动力学。添加 H2O2 电子受体可以显著提高 MIL-88A 的光催化 MB 脱色性能。此外,MIL-88A 在连续使用四次后对 MB 脱色仍表现出非常稳定的活性。由于具有可见光响应、低成本和丰富的天然来源等优点,这种活性 MIL-88A MOF 光催化剂在环境净化方面具有很大的潜力。

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