Sarr Modou, Diallo Waly, Diasse-Sarr Aminata, Plasseraud Laurent, Cattey Hélène
Laboratoire de Chimie Minérale et Analytique (LACHIMIA), Département de Chimie, Faculté des Sciences et Techniques, Université Cheikh Anta Diop, Dakar, Senegal.
ICMUB UMR 6302, Université de Bourgogne, Faculté des Sciences, 9 avenue Alain Savary, 21000 Dijon, France.
Acta Crystallogr Sect E Struct Rep Online. 2013 Oct 5;69(Pt 11):m581-2. doi: 10.1107/S1600536813026901.
The crystal structure of the title compound, (C6H14N)3[Sn(C2O4)2Cl2]Cl·H2O, contains three cyclo-hexyl-ammonium cations, one stannate(IV) dianion, one isolated chloride anion and one lattice water mol-ecule. The cyclo-hexyl-ammonium cations adopt chair conformations. In the complex anion, two bidentate oxalate ligands and two chloride anions in cis positions coordinate octa-hedrally to the central Sn(IV) atom. The cohesion of the mol-ecular entities is ensured by the formation of N-H⋯O, O-H⋯O, O-H⋯Cl and N-H⋯Cl inter-actions involving cations, anions and the lattice water mol-ecule, giving rise to a layer-like arrangement parallel to (010).
标题化合物（C6H14N）3[Sn(C2O4)2Cl2]Cl·H2O的晶体结构包含三个环己基铵阳离子、一个二价锡酸根阴离子、一个孤立的氯离子和一个晶格水分子。环己基铵阳离子呈椅式构象。在复合阴离子中，两个顺式的双齿草酸根配体和两个氯离子八面体配位到中心Sn(IV)原子上。分子实体之间通过涉及阳离子、阴离子和晶格水分子的N-H⋯O、O-H⋯O、O-H⋯Cl和N-H⋯Cl相互作用得以凝聚，形成平行于(010)的层状排列。
