Sarr Modou, Merkens Carina, Diassé-Sarr Aminata, Diop Libasse, Englert Ulli
Laboratoire de Chimie Minerale et Analytique, Département de Chimie, Faculté des Sciences et Techniques Université Cheikh Anta Diop, Dakar, Senegal.
Institut für Anorganische Chemie, RWTH Aachen University, Landoltweg 1, 52074 Aachen, Germany.
Acta Crystallogr Sect E Struct Rep Online. 2014 May 17;70(Pt 6):m220-1. doi: 10.1107/S160053681401109X. eCollection 2014 Jun 1.
The title compound, (C6H14N)2[Sn(C6H5)2Cl4], contains cyclo-hexyl-ammonium cations in general positions and a stannate(IV) anion that is located on a twofold rotation axis. The Sn(IV) atom in the complex anion is surrounded by four Cl(-) ligands and two trans-phenyl groups in a distorted octa-hedral configuration. The anions are connected with the cations through N-H⋯Cl hydrogen bonds. Every cation is involved in three N-H⋯Cl bonds to the chloride ligands of three different anions, and each chloride ligand is linked to two cations. This arrangement leads to a layered structure parallel to (010).
标题化合物 (C6H14N)2[Sn(C6H5)2Cl4] 中，环己基铵阳离子处于一般位置，而锡酸根(IV)阴离子位于二重旋转轴上。复合阴离子中的Sn(IV)原子被四个Cl(-)配体和两个反式苯基围绕，呈扭曲的八面体构型。阴离子通过N-H⋯Cl氢键与阳离子相连。每个阳离子与三个不同阴离子的氯配体形成三个N-H⋯Cl键，每个氯配体与两个阳离子相连。这种排列导致形成平行于(010)的层状结构。
