TU Dortmund, Anorganische Chemie, Otto-Hahn-Str. 6, 44149 Dortmund, Germany.
Chem Commun (Camb). 2014 Mar 7;50(19):2532-4. doi: 10.1039/c3cc48873j. Epub 2014 Jan 27.
New diamine coordination compounds with phenyllithium and allyllithium are presented. One of them is the first diamine complex containing two different, simple organolithium reagents. The formation of this unexpected compound is explained using quantum chemical calculations.
介绍了带有苯锂和烯丙基锂的新型二胺配位化合物。其中之一是第一个含有两种不同简单有机锂试剂的二胺配合物。使用量子化学计算解释了这种意外化合物的形成。
