钯催化的环状烯醇醚的动力学拆分。一种对映选择性合成功能化吡喃的方法。
Pd-Catalyzed kinetic resolution of cyclic enol ethers. An enantioselective route to functionalised pyrans.
机构信息
Department of Chemistry, University of Sheffield, Brook Hill, Sheffield, S3 7HF, UK.
出版信息
Chem Commun (Camb). 2014 Mar 14;50(21):2735-7. doi: 10.1039/c4cc00109e.
PMID:24473485
Abstract
Functionalised cyclic enol ethers can be recovered with high levels of enantiocontrol after an asymmetric catalytic [1,3]-rearrangement reaction. These compounds can be further elaborated to a series of carbo- and heterocyclic products in good yield and with excellent levels of stereocontrol.
摘要
经不对称催化[1,3]-重排反应后，功能化环状烯醇醚可以高对映选择性回收。这些化合物可以进一步衍生为一系列碳环和杂环产物，产率高，立体选择性好。
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