Nanodevice Laboratory, School of Electrical and Electronic Engineering, and §Nanobio Device Laboratory, School of Electrical and Electronic Engineering, Yonsei University , Seodaemun-Gu, Seoul 120-749, Republic of Korea.
ACS Appl Mater Interfaces. 2014 Feb 26;6(4):2764-9. doi: 10.1021/am4052987. Epub 2014 Feb 11.
Without introducing defects in the monolayer of carbon lattice, the deposition of high-κ dielectric material is a significant challenge because of the difficulty of high-quality oxide nucleation on graphene. Previous investigations of the deposition of high-κ dielectrics on graphene have often reported significant degradation of the electrical properties of graphene. In this study, we report a new way to integrate high-κ dielectrics with graphene by transferring a high-κ dielectric nanosheet onto graphene. Al2O3 film was deposited on a sacrificial layer using an atomic layer deposition process and the Al2O3 nanosheet was fabricated by removing the sacrificial layer. Top-gated graphene field-effect transistors were fabricated and characterized using the Al2O3 nanosheet as a gate dielectric. The top-gated graphene was demonstrated to have a field-effect mobility up to 2200 cm(2)/(V s). This method provides a new method for high-performance graphene devices with broad potential impacts reaching from high-frequency high-speed circuits to flexible electronics.
在不引入碳原子层单层缺陷的情况下,由于在石墨烯上高质量氧化物成核的困难,高κ介电材料的沉积是一个重大挑战。先前关于在石墨烯上沉积高κ电介质的研究经常报告石墨烯的电性能显著下降。在这项研究中,我们报告了一种通过将高κ介电纳米片转移到石墨烯上来与石墨烯集成高κ介电材料的新方法。使用原子层沉积工艺在牺牲层上沉积 Al2O3 薄膜,并通过去除牺牲层来制造 Al2O3 纳米片。使用 Al2O3 纳米片作为栅介质制造顶栅石墨烯场效应晶体管并对其进行了表征。所制造的顶栅石墨烯表现出高达 2200 cm2/(V s)的场效应迁移率。这种方法为高性能石墨烯器件提供了一种新方法,其潜在影响广泛,从高频高速电路到柔性电子学。