铜催化保护苯胺与仲胺的邻位 C-H 胺化反应。
Copper-catalyzed ortho-C-H amination of protected anilines with secondary amines.
机构信息
Departamento de Química Orgánica, Universidad Autónoma de Madrid, Cantoblanco, 28049 Madrid, Spain.
出版信息
Chem Commun (Camb). 2014 Mar 14;50(21):2801-3. doi: 10.1039/c3cc49633c.
PMID:24488142
Abstract
A practical Cu-catalyzed picolinamide-directed o-amination of anilines showing excellent mono-substitution selectivity and high functional group tolerance has been developed.
摘要
发展了一种实用的 Cu 催化的吡啶酰胺导向的苯胺邻位胺化反应，表现出优异的单取代选择性和高官能团容忍性。
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