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一种阳离子-阳离子共表面活性剂模板法,用于合成具有可调节层数的规则的多层囊泡状硅。

A cationic-cationic co-surfactant templating route for synthesizing well-defined multilamellar vesicular silica with an adjustable number of layers.

机构信息

Key Laboratory of Fine Chemicals in Universities of Shandong, School of Chemistry and Pharmaceutical Engineering, Qilu University of Technology, Jinan, P. R. China.

出版信息

Chem Commun (Camb). 2014 Mar 18;50(22):2907-9. doi: 10.1039/c3cc49511f. Epub 2014 Feb 4.

Abstract

Vesicular mesoporous silica with well-defined multilamellar structures was prepared using didodecyldimethylammonium bromide (DDAB)/cetyltrimethylammonium bromide (CTAB) as a structure-directing agent. The number of vesicular silica layers can be tuned from 7 to 2 by changing the molar ratio of DDAB to CTAB.

摘要

采用二癸基二甲基溴化铵(DDAB)/十六烷基三甲基溴化铵(CTAB)作为结构导向剂,制备了具有明确定义的多层结构的囊泡介孔硅。通过改变 DDAB 与 CTAB 的摩尔比,可将囊泡硅层的数量从 7 层调至 2 层。

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