The coordination polymer poly[[aqua(μ-oxalato)[1H-1,2,4-triazole-5(4H)-thione]cadmium(II)] monohydrate].
作者信息
Liang Qian, Wang Yu-Lin, Zhao Yan, Cao Gao-Juan
机构信息
Jinshan College of Fujian Agriculture and Forestry University, Fuzhou, Fujian 350002, People's Republic of China.
College of Life Science, Fujian Agriculture and Forestry University, Fuzhou, Fujian 350002, People's Republic of China.
出版信息
Acta Crystallogr C Struct Chem. 2014 Feb;70(Pt 2):182-4. doi: 10.1107/S2053229614000102. Epub 2014 Jan 11.
The title complex, {[Cd(C2O4)(C2H3N3S)(H2O)]·H2O}n, has a two-dimensional metal-organic framework, with the Cd(II) cation coordinated by three oxalate ligands, a 1H-1,2,4-triazole-5(4H)-thione (H2trzS) ligand and a water molecule. The CdO6S and oxalate units form an extended two-dimensional layered structure, with the terminal H2trzS ligands bonded to the Cd(II) sites through the thione S atoms. Hydrogen-bond interactions exist between adjacent layers.
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