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青藏高原东缘若尔盖高寒草地表土中有机氯农药和多氯联苯的分布特征

Organochlorine pesticides and polychlorinated biphenyls in surface soils from Ruoergai high altitude prairie, east edge of Qinghai-Tibet Plateau.

机构信息

National Research Center for Geoanalysis, Beijing 100037, China.

National Research Center for Geoanalysis, Beijing 100037, China.

出版信息

Sci Total Environ. 2014 Apr 15;478:90-7. doi: 10.1016/j.scitotenv.2014.01.002. Epub 2014 Feb 12.

DOI:10.1016/j.scitotenv.2014.01.002
PMID:24530588
Abstract

Organochlorine pesticides (OCPs) and polychlorinated biphenyls (PCBs) in surface soils along a transect from source areas (a petro-chemical industrial city, Lanzhou and its adjacent agricultural areas) to Ruoergai highland prairie (3,552 m above sea level (a.s.l.)), where livestock farming was the only human economic activity, were studied. OCPs in Ruoergai soils were dominated by HCHs. The land types, organic carbon contents and pH affected the POP preservation in soil. OCPs and PCBs in surface soils in Ruoergai wetland and grassland showed different contamination patterns; OCP levels in wetland soils were higher than those in grassland. Significant correlations were observed between total organic carbon (TOC) contents and PCB concentrations in the soils. The land type determines TOC content in soils, which in turn was a major factor on soil concentrations of POPs. The transect was divided into two sections: The first section (Gradient I) is from Lanzhou (1,740 ma.s.l.) to Luqu (2,400 ma.s.l.) with decreasing agricultural activities, and the second section (Gradient II) is from Luqu to Ruoergai (3,500 ma.s.l.) with grassland as the main land type. Soils of Ruoergai area were dominated by α-HCH, β-HCH, HCB, and PCB28, suggesting that the behaviors of POPs in the high plateau region were different from high mountain cold-trapping effect, and that the POPs' behaviors in high plateau region were similar to Polar Regions.

摘要

对沿兰州(海拔 1740 米)- 若尔盖(海拔 3500 米)高原有石油化工工业城市、兰州及其相邻农业区向若尔盖高原草原(海拔 3552 米)的一条横断线上的表层土壤中的有机氯农药(OCPs)和多氯联苯(PCBs)进行了研究。若尔盖土壤中的 OCPs 主要为 HCHs。土地类型、有机碳含量和 pH 值影响了土壤中持久性有机污染物的保留。若尔盖湿地和草原表层土壤中的 OCPs 和 PCBs 表现出不同的污染模式;湿地土壤中的 OCP 水平高于草原。土壤中总有机碳(TOC)含量与 PCB 浓度之间存在显著相关性。土地类型决定了土壤中的 TOC 含量,而 TOC 含量又是土壤中持久性有机污染物浓度的主要因素。该横断带分为两段:第一段(梯度 I)从兰州(海拔 1740 米)到碌曲(海拔 2400 米),农业活动减少,第二段(梯度 II)从碌曲到若尔盖(海拔 3500 米),主要土地类型为草原。若尔盖地区的土壤以 α-HCH、β-HCH、HCB 和 PCB28 为主,表明高原地区持久性有机污染物的行为与高山冷阱效应不同,高原地区持久性有机污染物的行为与极地相似。

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