硅二醇与双功能杂环的超分子氢键组装。
Supramolecular hydrogen-bonding assembly of silanediols with bifunctional heterocycles.
机构信息
Department of Chemistry, University of California, One Shields Avenue, Davis, California 95616, USA.
出版信息
Chem Commun (Camb). 2014 Apr 11;50(28):3738-40. doi: 10.1039/c4cc00672k.
PMID:24577634
Abstract
X-ray crystallography showcases the distinct self-association and hydrogen-bonding patterns of organic silanediols, R2Si(OH)2, with bifunctional heterocycles for supramolecular assembly. Diffusion-ordered spectroscopy (DOSY) studies identify the dominant hydrogen-bonding patterns and structures in solution, which correlate with solid-state patterns at high concentrations.
摘要
X 射线晶体学展示了有机硅烷二醇 R2Si(OH)2 与双功能杂环的独特自组装和氢键模式，用于超分子组装。扩散排序光谱（DOSY）研究确定了溶液中主要的氢键模式和结构，这些模式与高浓度下的固态模式相关。
Zotero 插件