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采用犁头草(Leersia hexandra Swartz)构建湿地对电镀废水中的 Cr、Cu 和 Ni 的去除的可行性研究。

Feasibility of constructed wetland planted with Leersia hexandra Swartz for removing Cr, Cu and Ni from electroplating wastewater.

机构信息

Institute of Light Industry and Food Engineering, Guangxi University, Nanning, Guangxi 530004, People's Republic of China.

Guangxi Key Laboratory of Environmental Pollution Control Theory and Technology, Guilin University of Technology, Guilin, Guangxi 541004, People's Republic of China.

出版信息

Environ Technol. 2014 Jan-Feb;35(1-4):187-94. doi: 10.1080/09593330.2013.822006.

Abstract

As a low-cost treatment technology for effluent, the constructed wetlands can be applied to remove the heavy metals from wastewater. Leersia hexandra Swartz is a metal-accumulating hygrophyte with great potential to remove heavy metal from water. In this study, two pilot-scale constructed wetlands planted with L. hexandra (CWL) were set up in greenhouse to treat electroplating wastewater containing Cr, Cu and Ni. The treatment performance of CWL under different hydraulic loading rates (HLR) and initial metal concentrations were also evaluated. The results showed that CWL significantly reduced the concentrations of Cr, Cu and Ni in wastewater by 84.4%, 97.1% and 94.3%, respectively. High HLR decreased the removal efficiencies of Cr, Cu and Ni; however, the heavy metal concentrations in effluent met Emission Standard of Pollutants for Electroplating in China (ESPE) at HLR less than 0.3 m3/m2 d. For the influent of 5 mg/L Cr, 10 mg/L Cu and 8 mg/L Ni, effluent concentrations were below maximum allowable concentrations in ESPE, indicating that the removal of Cr, Cu and Ni by CWL was feasible at considerably high influent metal concentrations. Mass balance showed that the primary sink for the retention of contaminants within the constructed wetland system was the sediment, which accounted for 59.5%, 83.5%, and 73.9% of the Cr, Cu and Ni, respectively. The data from the pilot wetlands support the view that CWL could be used to successfully remove Cr, Cu and Ni from electroplating wastewater.

摘要

作为一种低成本的废水处理技术,人工湿地可用于去除废水中的重金属。李氏禾是一种具有重金属富集能力的喜水植物,具有从水中去除重金属的巨大潜力。本研究在温室中建立了两个种植李氏禾的中试规模人工湿地(CWL),以处理含 Cr、Cu 和 Ni 的电镀废水。还评估了 CWL 在不同水力负荷率(HLR)和初始金属浓度下的处理性能。结果表明,CWL 可使电镀废水中的 Cr、Cu 和 Ni 浓度分别显著降低 84.4%、97.1%和 94.3%。高 HLR 降低了 Cr、Cu 和 Ni 的去除效率;然而,在 HLR 小于 0.3 m3/m2 d 时,出水重金属浓度符合《电镀污染物排放标准》(ESPE)。对于 5 mg/L Cr、10 mg/L Cu 和 8 mg/L Ni 的进水,出水浓度低于 ESPE 的最大允许浓度,表明 CWL 可在相当高的进水金属浓度下去除 Cr、Cu 和 Ni。质量平衡表明,污染物在人工湿地系统中的主要滞留汇是沉积物,Cr、Cu 和 Ni 的含量分别占 59.5%、83.5%和 73.9%。中试湿地的数据支持了 CWL 可成功去除电镀废水中的 Cr、Cu 和 Ni 的观点。

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