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通过金属配体策略逐步组装 Pd(6)(RuL(3))(8)纳米级的菱形十二面体金属有机笼，用于客体捕获和保护。

Stepwise assembly of Pd(6)(RuL(3))(8) nanoscale rhombododecahedral metal-organic cages via metalloligand strategy for guest trapping and protection.

机构信息

MOE Laboratory of Bioinorganic and Synthetic Chemistry, State Key Laboratory of Optoelectronic Materials and Technologies, Lehn Institute of Functional Materials, School of Chemistry and Chemical Engineering, Sun Yat-Sen University , Guangzhou 510275, China.

出版信息

J Am Chem Soc. 2014 Mar 26;136(12):4456-9. doi: 10.1021/ja410044r. Epub 2014 Mar 17.

DOI:10.1021/ja410044r
PMID:24611560
Abstract

Stepwise synthesis of nanosized Pd-Ru heteronuclear metal-organic cages from predesigned redox- and photo-active Ru(II)-metalloligand and naked Pd(II) ion is described. The resulting cage shows rhombododecahedral shape and contains a 5350 Å(3) cavity and 12 open windows, facilitating effective trapping of both polar and nonpolar guest molecules. Protection of photosensitive guests against UV radiation is studied.

摘要

分步合成纳米 Pd-Ru 杂核金属有机笼，由预先设计的氧化还原和光活性 Ru(II)-金属配位体和裸露的 Pd(II)离子组成。所得笼具有菱十二面体形状，包含一个 5350 Å(3)的空腔和 12 个开口窗，有利于有效捕获极性和非极性客体分子。研究了对光敏客体的保护作用，以防止其受到 UV 辐射。

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