Riclea Ramona, Citron Christian A, Rinkel Jan, Dickschat Jeroen S
Institut für Organische Chemie, Hagenring 30, 38106 Braunschweig, Germany.
Chem Commun (Camb). 2014 Apr 25;50(32):4228-30. doi: 10.1039/c4cc00177j.
The recently developed CLSA-NMR technique that is based on feeding experiments with (13)C-labelled precursors was applied in the identification of isoafricanol as the main volatile terpene emitted by Streptomyces violaceusniger. The isoafricanol synthase of this organism is presented, together with a recent phylogenetic analysis of bacterial terpene cyclases.
最近开发的基于用(13)C标记前体进行喂养实验的CLSA-NMR技术,被用于鉴定异非洲醇是紫黑链霉菌释放的主要挥发性萜类化合物。本文介绍了该生物体的异非洲醇合酶,以及最近对细菌萜类环化酶的系统发育分析。