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用于植入式除颤器的锂/银钒氧化物电池。

Lithium/silver vanadium oxide batteries for implantable defibrillators.

作者信息

Takeuchi E S, Quattrini P J, Greatbatch W

机构信息

Wilson Greatbatch Ltd., Clarence, New York 14031.

出版信息

Pacing Clin Electrophysiol. 1988 Nov;11(11 Pt 2):2035-9. doi: 10.1111/j.1540-8159.1988.tb06346.x.

DOI:10.1111/j.1540-8159.1988.tb06346.x
PMID:2463584
Abstract

Lithium/silver vanadium oxide (SVO) batteries have been under development in these laboratories since 1980. The system consists of a lithium anode, a liquid organic electrolyte, a cathode composed of conductive additives, a binder, and silver vanadium oxide, a vanadium oxide bronze produced by the thermal decomposition of vanadium oxide and silver nitrate. High rate batteries for implantable cardiac defibrillators based on this chemistry have been under development since 1984. The first Li/SVO defibrillator battery introduced was the Model 8512 with a theoretical capacity of 5.5 Ah and dimensions of 52 mm X 33 mm X 13.5 mm. Later, the Model 8615 was introduced. This cell has a theoretical capacity of 3.0 Ah and dimensions of 52 mm X 21 mm X 13.5 mm. Two other cells which are proprietary have also been introduced. All of the cells can deliver pulses of up to 2.0 amps from a microampere background. The self-discharge of the cells has been shown to be less than 2% per year. In addition, the silver vanadium oxide chemistry provides a discharge curve whose voltage decreases with depth of discharge. This feature can be used as a state-of-charge indicator. The cells have been subjected to rigorous environmental and abuse testing and have been found to have characteristics suitable for implantable applications.

摘要

自1980年起,这些实验室就一直在研发锂/银钒氧化物(SVO)电池。该系统由锂阳极、液体有机电解质、由导电添加剂、粘合剂和银钒氧化物组成的阴极、通过氧化钒和硝酸银的热分解产生的氧化钒青铜组成。自1984年以来,一直在研发基于这种化学原理的用于植入式心脏除颤器的高功率电池。推出的首款锂/银钒氧化物除颤器电池是8512型,理论容量为5.5安时,尺寸为52毫米×33毫米×13.5毫米。后来,又推出了8615型。该电池的理论容量为3.0安时,尺寸为52毫米×21毫米×13.5毫米。还推出了另外两款专利电池。所有这些电池都能在微安级背景电流下提供高达2.0安培的脉冲。已证明这些电池的自放电率每年低于2%。此外,银钒氧化物化学性质提供了一种放电曲线,其电压随放电深度降低。这一特性可用作荷电状态指示器。这些电池已经历了严格的环境和滥用测试,并且已发现具有适合植入式应用的特性。

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