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热解温度对空果串和稻壳生物炭理化性质的影响。

Effects of pyrolysis temperature on the physicochemical properties of empty fruit bunch and rice husk biochars.

作者信息

Claoston N, Samsuri A W, Ahmad Husni M H, Mohd Amran M S

机构信息

1Department of Land Management, Faculty of Agriculture, Universiti Putra Malaysia, Selangor Darul Ehsan, Malaysia.

出版信息

Waste Manag Res. 2014 Apr;32(4):331-9. doi: 10.1177/0734242X14525822. Epub 2014 Mar 18.

Abstract

Biochar has received great attention recently due to its potential to improve soil fertility and immobilize contaminants as well as serving as a way of carbon sequestration and therefore a possible carbon sink. In this work, a series of biochars were produced from empty fruit bunch (EFB) and rice husk (RH) by slow pyrolysis at different temperatures (350, 500, and 650°C) and their physicochemical properties were analysed. The results indicate that porosity, ash content, electrical conductivity (EC), and pH value of both EFB and RH biochars were increased with temperature; however, yield, cation exchange capacity (CEC), and H, C, and N content were decreased with increasing pyrolysis temperature. The Fourier transform IR spectra were similar for both RH and EFB biochars but the functional groups were more distinct in the EFB biochar spectra. There were reductions in the amount of functional groups as pyrolysis temperature increased especially for the EFB biochar. However, total acidity of the functional groups increased with pyrolysis temperature for both biochars.

摘要

由于生物炭具有改善土壤肥力、固定污染物的潜力,以及作为一种碳固存方式进而成为可能的碳汇,其最近受到了极大关注。在这项工作中,通过在不同温度(350、500和650°C)下缓慢热解,由空果串(EFB)和稻壳(RH)制备了一系列生物炭,并对其物理化学性质进行了分析。结果表明,EFB和RH生物炭的孔隙率、灰分含量、电导率(EC)和pH值均随温度升高而增加;然而,产率、阳离子交换容量(CEC)以及H、C和N含量则随热解温度升高而降低。RH和EFB生物炭的傅里叶变换红外光谱相似,但功能团在EFB生物炭光谱中更为明显。随着热解温度升高,功能团数量减少,尤其是EFB生物炭。然而,两种生物炭功能团的总酸度均随热解温度升高而增加。

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