Centre for Surface Chemistry and Catalysis, KU Leuven, Arenbergpark 23, B-3001 Leuven, Belgium.
Chem Soc Rev. 2014 Aug 21;43(16):5766-88. doi: 10.1039/c4cs00006d.
While much attention of the MOF community has been devoted to adsorption and purification of gases, there is now also a vast body of data on the capability of MOFs to separate and purify liquid mixtures. Initial studies focused on separation of petrochemicals in apolar backgrounds, but the attention has moved now to the separation of complex, e.g. chiral compounds, and to the isolation of biobased compounds from aqueous media. We here give an overview of most of the existing literature, with an accent on separation mechanisms and structure-selectivity relationships.
虽然 MOF 领域的研究主要集中在气体的吸附和净化上，但现在也有大量的数据表明 MOFs 能够分离和净化液体混合物。最初的研究集中在非极性背景下分离石油化工产品，但现在的注意力已经转移到分离复杂的，例如手性化合物，以及从水介质中分离生物基化合物。本文对现有的大部分文献进行了综述，重点介绍了分离机制和结构选择性关系。
