Cameron Robert P, Yao Alison M, Barnett Stephen M
School of Physics and Astronomy, University of Glasgow , Glasgow G12 8QQ, United Kingdom.
J Phys Chem A. 2014 May 15;118(19):3472-8. doi: 10.1021/jp500319x. Epub 2014 Apr 7.
We suggest the use of certain readily producible types of light to exert a force that points in opposite directions for the enantiomers of a chiral molecule and propose multiple devices based upon this novel manifestation of optical activity: in particular, our discriminatory chiral diffraction grating; a device that could be employed, for example, to measure the enantiomeric excess of a sample of chiral molecules simply and to high precision. Our work is relevant for many types of molecules and our proposed devices may be realizable using currently existing technology.
我们建议使用某些易于产生的光类型来施加一种力,该力对于手性分子的对映体指向相反的方向,并基于这种光活性的新表现提出了多种装置:特别是我们的鉴别性手性衍射光栅;一种例如可用于简单且高精度地测量手性分子样品对映体过量的装置。我们的工作适用于多种类型的分子,并且我们提出的装置可能使用现有技术实现。