Department of Chemistry, University of South Florida, 4202 East Flower Avenues, Tampa, Florida, USA.
Chem Soc Rev. 2014 Aug 21;43(16):5841-66. doi: 10.1039/c4cs00001c.
This review presents comprehensively recent progress in metal-metalloporphyrin frameworks (MMPFs) with an emphasis on versatile functionalities. Following a brief introduction of basic concepts and the potential virtues of MMPFs, we give a snapshot of the historical perspective of MMPFs since 1991. We then summarize four effective strategies implemented frequently to construct prototypal MMPFs. MMPFs represent a resurging class of promising functional materials, highlighted with diverse applications including guest-molecule adsorption and separation, catalysis, nano-thin films and light-harvesting.
这篇综述全面介绍了金属-金属卟啉骨架(MMPFs)的最新进展,重点介绍了其多功能性。在简要介绍了基本概念和 MMPFs 的潜在优点之后,我们概述了自 1991 年以来 MMPFs 的历史发展。然后,我们总结了经常采用的四种构建原型 MMPFs 的有效策略。MMPFs 是一类新兴的有前途的功能材料,具有多种应用,包括客体分子吸附和分离、催化、纳米薄膜和光捕获。