Schneemann Andreas, Henke Sebastian, Schwedler Inke, Fischer Roland A
Lehrstuhl für Anorganische Chemie II, Ruhr-Universität Bochum, Universitätsstraße 150, 44780 Bochum (Germany), Fax: (+49) 234-321-4174.
Chemphyschem. 2014 Apr 4;15(5):823-39. doi: 10.1002/cphc.201300976. Epub 2014 Mar 11.
Metal-organic frameworks are promising materials for manifold applications. This Minireview highlights approaches for the fine-tuning of specific sorption properties (e.g. capacity, selectivity, and breathing behavior) of this interesting class of materials. Central aspects covered are the control over the crystal morphology, the targeted tuning of sorption properties by judicious choice of metal centers and linkers, and the preparation of host-guest systems. We want to introduce the reader to these topics on the basis of the manipulation of a handful of outstanding prototypical metal-organic frameworks.
金属有机框架是具有多种应用前景的材料。本综述重点介绍了对这类有趣材料的特定吸附特性（如容量、选择性和呼吸行为）进行微调的方法。涵盖的核心方面包括对晶体形态的控制、通过明智选择金属中心和连接体对吸附特性进行有针对性的调节，以及主客体体系的制备。我们希望基于对少数几种杰出的典型金属有机框架的操控，向读者介绍这些主题。
