磷化氢引发的多米诺反应：一种制备螺环戊酮的简便方法。
Phosphine-initiated domino reaction: a convenient method for the preparation of spirocyclopentanones.
作者信息
Liang Ling, Li Erqing, Xie Peizhong, Huang You
机构信息
State Key Laboratory and Institute of Elemento-organic chemistry Collaborative Innovation Center of Science and Engineering (Tianjin), Nankai University, Tianjin 30071 (China), Fax: (+86) 22-23503627.
出版信息
Chem Asian J. 2014 May;9(5):1270-3. doi: 10.1002/asia.201301641. Epub 2014 Feb 23.
PMID:24678009
Abstract
An efficient synthetic approach has been developed for the construction of the spirocyclopentanone skeleton via a phosphine-catalyzed [3+2] annulation reaction. With this novel and economical protocol, various quaternary carbon-centered spirocyclopentanones could be readily obtained.
摘要
已经开发出一种有效的合成方法，通过膦催化的[3+2]环化反应构建螺环戊酮骨架。采用这种新颖且经济的方案，可以很容易地获得各种以季碳为中心的螺环戊酮。
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