磷化氢引发的多米诺反应：一种制备螺环戊酮的简便方法。
Phosphine-initiated domino reaction: a convenient method for the preparation of spirocyclopentanones.
作者信息
Liang Ling, Li Erqing, Xie Peizhong, Huang You
机构信息
State Key Laboratory and Institute of Elemento-organic chemistry Collaborative Innovation Center of Science and Engineering (Tianjin), Nankai University, Tianjin 30071 (China), Fax: (+86) 22-23503627.
出版信息
Chem Asian J. 2014 May;9(5):1270-3. doi: 10.1002/asia.201301641. Epub 2014 Feb 23.
PMID:24678009
Abstract
An efficient synthetic approach has been developed for the construction of the spirocyclopentanone skeleton via a phosphine-catalyzed [3+2] annulation reaction. With this novel and economical protocol, various quaternary carbon-centered spirocyclopentanones could be readily obtained.
摘要
已经开发出一种有效的合成方法，通过膦催化的[3+2]环化反应构建螺环戊酮骨架。采用这种新颖且经济的方案，可以很容易地获得各种以季碳为中心的螺环戊酮。
相似文献
1
Phosphine-initiated domino reaction: a convenient method for the preparation of spirocyclopentanones.磷化氢引发的多米诺反应：一种制备螺环戊酮的简便方法。
Chem Asian J. 2014 May;9(5):1270-3. doi: 10.1002/asia.201301641. Epub 2014 Feb 23.
2
Phosphine-catalyzed [3 + 2] and [4 + 2] annulation reactions of ynones with barbiturate-derived alkenes.磷化氢催化的炔酮与巴比妥酸衍生烯烃的[3 + 2]和[4 + 2]环化反应。
Org Biomol Chem. 2017 Jun 27;15(25):5298-5307. doi: 10.1039/c7ob01034f.
3
Phosphine-catalyzed domino reaction: an efficient method for the synthesis of highly functionalized spirooxazolines.膦催化的串联反应：一种高效合成高官能化螺噁唑啉的方法。
Org Biomol Chem. 2012 Oct 7;10(37):7628-34. doi: 10.1039/c2ob26338f. Epub 2012 Aug 17.
4
Phosphine-catalyzed sequential annulation domino reaction: rapid construction of bicyclo[4.1.0]heptene skeletons.膦催化的串联环化多米诺反应：双环[4.1.0]庚烯骨架的快速构建
Chem Commun (Camb). 2014 Jun 1;50(43):5710-3. doi: 10.1039/c4cc01097c. Epub 2014 Apr 15.
5
Phosphine-catalyzed Rauhut-Currier domino reaction: a facile strategy for the construction of carbocyclic spirooxindoles skeletons.膦催化的 Rauhut-Currier 串联反应：构建碳环螺环氧化吲哚骨架的简便策略。
Chem Asian J. 2013 Sep;8(9):1981-4. doi: 10.1002/asia.201300650. Epub 2013 Jun 28.
6
Phosphine-catalyzed domino reaction: a novel sequential [2+3] and [3+2] annulation reaction of γ-substituent allenoates to construct bicyclic[3, 3, 0]octene derivatives.膦催化的多米诺反应：γ-取代烯丙酸盐的新型串联[2+3]和[3+2]环化反应，构建双环[3,3,0]辛烯衍生物。
Chem Commun (Camb). 2014 Jan 28;50(8):948-50. doi: 10.1039/c3cc47716a.
7
Bifunctional phosphine-catalyzed cross-Rauhut-Currier/Michael/aldol condensation triple domino reaction: synthesis of functionalized cyclohexenes.双功能膦催化的交叉 Rauhut-Currier/Michael/aldol 缩合三重多米诺反应：官能化环己烯的合成。
Org Biomol Chem. 2011 Oct 7;9(19):6707-14. doi: 10.1039/c1ob05693j. Epub 2011 Aug 11.
8
An unexpected phosphine-catalyzed [3 + 2] annulation. Synthesis of highly functionalized cyclopentenes.一种意外的膦催化[3+2]环化反应。高官能化环戊烯的合成。
Org Lett. 2008 Aug 7;10(15):3267-70. doi: 10.1021/ol8011452. Epub 2008 Jul 3.
9
Phosphine-catalyzed Rauhut-Currier domino reaction: a facile strategy for the construction of highly functionalized cyclopentene.膦催化的劳乌特-库里尔多米诺反应：构建高度官能化环戊烯的简便策略。
Chem Asian J. 2012 Sep;7(9):2032-5. doi: 10.1002/asia.201200308. Epub 2012 Jun 12.
10
Phosphine-catalyzed [4+1] annulation of 1,3-(aza)dienes with maleimides: highly efficient construction of azaspiro[4.4]nonenes.膦催化的1,3-（氮杂）二烯与马来酰亚胺的[4+1]环化反应：氮杂螺[4.4]壬烯的高效构建
Chem Commun (Camb). 2014 Nov 14;50(88):13506-9. doi: 10.1039/c4cc05624h.
引用本文的文献
1
Phosphine-Promoted Synthesis of Naphthoquinones Fused with Cyclopentadienyl Moiety Via Ring Expansion: Synthesis, Reactivity, and Ring Contraction Via [1,5] Sigmatropic Rearrangement.膦促进的通过扩环合成与环戊二烯基部分稠合的萘醌：合成、反应性以及通过[1,5] 迁移重排的环收缩
Org Lett. 2024 Oct 18;26(41):8730-8735. doi: 10.1021/acs.orglett.4c03052. Epub 2024 Oct 7.
2
Indane-1,3-Dione: From Synthetic Strategies to Applications.丙烷-1,3-二酮：从合成策略到应用。
Molecules. 2022 Sep 14;27(18):5976. doi: 10.3390/molecules27185976.
3
Phosphine-Catalyzed α-Umpolung-Aldol Reaction for the Synthesis of Benzo[ b]azapin-3-ones.膦催化的α-Umpolung-aldol 反应在苯并[ b]氮杂卓-3-酮合成中的应用。
Org Lett. 2019 Jul 5;21(13):5143-5146. doi: 10.1021/acs.orglett.9b01749. Epub 2019 Jun 20.
4
Phosphine Organocatalysis.膦有机催化。
Chem Rev. 2018 Oct 24;118(20):10049-10293. doi: 10.1021/acs.chemrev.8b00081. Epub 2018 Sep 27.
Zotero 插件