Wang Jing, Liu Chao, Yuan Jiwen, Lei Aiwen
College of Chemistry and Molecular Sciences, Wuhan University, Wuhan, Hubei 430072, P. R. China.
Chem Commun (Camb). 2014 May 11;50(36):4736-9. doi: 10.1039/c4cc01447b.
A novel oxidative coupling of aldehydes with simple amides, most likely involving a radical process, was achieved through the use of an iron catalyst. Various amides were utilized as substrates to easily construct imides by coupling with aldehydes. A catalytic cycle involving the benzoyl halide intermediate is proposed based on our experimental results.
通过使用铁催化剂实现了醛与简单酰胺的新型氧化偶联反应，该反应很可能涉及自由基过程。各种酰胺被用作底物，通过与醛偶联轻松构建酰亚胺。根据我们的实验结果，提出了一个涉及苯甲酰卤中间体的催化循环。
