Xu Xiaofei, Ting Christina L, Kusaka Isamu, Wang Zhen-Gang
Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, California 91125; email:
Annu Rev Phys Chem. 2014;65:449-75. doi: 10.1146/annurev-physchem-032511-143750.
Nucleation is a ubiquitous phenomenon in many physical, chemical, and biological processes. In this review, we describe recent progress on the theoretical study of nucleation in polymeric fluids and soft matter, including binary mixtures (polymer blends, polymers in poor solvents, compressible polymer-small molecule mixtures), block copolymer melts, and lipid membranes. We discuss the methodological development for studying nucleation as well as novel insights and new physics obtained in the study of the nucleation behavior in these systems.
成核是许多物理、化学和生物过程中普遍存在的现象。在这篇综述中,我们描述了聚合物流体和软物质中成核理论研究的最新进展,包括二元混合物(聚合物共混物、不良溶剂中的聚合物、可压缩聚合物-小分子混合物)、嵌段共聚物熔体和脂质膜。我们讨论了研究成核的方法学发展,以及在这些系统的成核行为研究中获得的新见解和新物理现象。