School of Environmental Science & Engineering, Shanghai Jiao Tong University, 800 Dongchuan Road, Shanghai 200240, China.
School of Environmental Science & Engineering, Shanghai Jiao Tong University, 800 Dongchuan Road, Shanghai 200240, China.
Waste Manag. 2014 Aug;34(8):1455-69. doi: 10.1016/j.wasman.2014.03.004. Epub 2014 Apr 13.
The world's waste electrical and electronic equipment (WEEE) consumption has increased incredibly in recent decades, which have drawn much attention from the public. However, the major economic driving force for recycling of WEEE is the value of the metallic fractions (MFs). The non-metallic fractions (NMFs), which take up a large proportion of E-wastes, were treated by incineration or landfill in the past. NMFs from WEEE contain heavy metals, brominated flame retardant (BFRs) and other toxic and hazardous substances. Combustion as well as landfill may cause serious environmental problems. Therefore, research on resource reutilization and safe disposal of the NMFs from WEEE has a great significance from the viewpoint of environmental protection. Among the enormous variety of NMFs from WEEE, some of them are quite easy to recycle while others are difficult, such as plastics, glass and NMFs from waste printed circuit boards (WPCBs). In this paper, we mainly focus on the intractable NMFs from WEEE. Methods and technologies of recycling the two types of NMFs from WEEE, plastics, glass are reviewed in this paper. For WEEE plastics, the pyrolysis technology has the lowest energy consumption and the pyrolysis oil could be obtained, but the containing of BFRs makes the pyrolysis recycling process problematic. Supercritical fluids (SCF) and gasification technology have a potentially smaller environmental impact than pyrolysis process, but the energy consumption is higher. With regard to WEEE glass, lead removing is requisite before the reutilization of the cathode ray tube (CRT) funnel glass, and the recycling of liquid crystal display (LCD) glass is economically viable for the containing of precious metals (indium and tin). However, the environmental assessment of the recycling process is essential and important before the industrialized production stage. For example, noise and dust should be evaluated during the glass cutting process. This study could contribute significantly to understanding the recycling methods of NMFs from WEEE and serve as guidance for the future technology research and development.
在最近几十年中,世界上废弃的电气和电子设备(WEEE)消费量令人难以置信地增加,引起了公众的极大关注。然而,回收 WEEE 的主要经济驱动力是金属部分(MFs)的价值。过去,WEEE 的非金属部分(NMFs)占很大比例,采用焚烧或填埋方式处理。WEEE 的 NMFs 含有重金属、溴化阻燃剂(BFRs)和其他有毒有害物质。燃烧和填埋可能会造成严重的环境问题。因此,从环境保护的角度出发,研究 WEEE 的 NMFs 的资源再利用和安全处置具有重要意义。在 WEEE 的大量 NMFs 中,有些比较容易回收,有些则比较困难,例如塑料、玻璃和废印刷电路板(WPCB)的 NMFs。本文主要关注难以回收的 WEEE 的 NMFs。本文综述了 WEEE 中这两种 NMFs(塑料、玻璃)的回收方法和技术。对于 WEEE 塑料,热解技术的能耗最低,可以得到热解油,但 BFRs 的存在使得热解回收过程存在问题。超临界流体(SCF)和气化技术比热解过程对环境的影响更小,但能耗更高。对于 WEEE 玻璃,在再利用阴极射线管(CRT)漏斗玻璃之前,需要去除铅,并且由于含有贵金属(铟和锡),液晶显示器(LCD)玻璃的回收具有经济可行性。然而,在工业化生产阶段之前,必须对回收过程进行环境评估。例如,在玻璃切割过程中应评估噪音和粉尘。这项研究对了解 WEEE 的 NMFs 回收方法有重要贡献,并为未来的技术研究和开发提供指导。