Tiwari Shashi, Singh Arun Kumar, Prakash Rajiv
J Nanosci Nanotechnol. 2014 Apr;14(4):2823-8. doi: 10.1166/jnn.2014.8570.
The major drawback of organic field effect transistors (OFETs) is its lower mobility, which restricts their applications for high performance devices. Recently, graphene exhibits excellent carrier mobility, therefore, is used as a novel electronic substance for the fundamental research and several potential applications. Pristine graphene is not applicable in field effect transistors (FETs) for satisfactory on/off current ratio as it has no forbidden energy gap. Here, we report the fabrication as well as characterizations of poly-3-hexylthiophene (P3HT)/graphene nanocomposite (with two distinct concentrations i.e., 0.05 and 0.1 mg/ml of graphene in P3HT solution) based FETs to over come the limitations. The current-voltage (I-V) characteristics of P3HT/graphene based FETs are measured and key performance parameters of device are compared against only polymer P3HT based FETs. The analysis demonstrates that, in P3HT/graphene transistors some crucial parameters such as drain saturation current and mobility enhanced drastically although the on/off ratio reduced significantly. Our study demonstrates that presence of graphene in organic semiconductor and a synergic effect due to uniform distribution in the nanospace is an ordinary route to achieve high mobility OFETs which impart an affordable way for raising the performance of organic transistors.
有机场效应晶体管(OFET)的主要缺点是其迁移率较低,这限制了它们在高性能器件中的应用。最近,石墨烯表现出优异的载流子迁移率,因此被用作一种新型电子材料用于基础研究和一些潜在应用。由于原始石墨烯没有禁带,所以它不适用于场效应晶体管(FET)以获得令人满意的开/关电流比。在此,我们报道了基于聚3-己基噻吩(P3HT)/石墨烯纳米复合材料(在P3HT溶液中有两种不同浓度,即0.05和0.1mg/ml的石墨烯)的FET的制备及其表征,以克服这些限制。测量了基于P3HT/石墨烯的FET的电流-电压(I-V)特性,并将器件的关键性能参数与仅基于聚合物P3HT的FET进行了比较。分析表明,在P3HT/石墨烯晶体管中,一些关键参数,如漏极饱和电流和迁移率大幅提高,尽管开/关比显著降低。我们的研究表明,有机半导体中石墨烯的存在以及由于在纳米空间中均匀分布而产生的协同效应是实现高迁移率OFET的常见途径,这为提高有机晶体管的性能提供了一种经济实惠的方法。