手性单链磁体：螺旋堆叠的[Mn(III)₂Cu(II)]三角形。
Chiral single-chain magnet: helically stacked [Mn(III)2Cu(II)] triangles.
作者信息
Shiga Takuya, Maruyama Kazuya, Newton Graham N, Inglis Ross, Brechin Euan K, Oshio Hiroki
机构信息
Graduate School of Pure and Applied Sciences, University of Tsukuba , Tennodai 1-1-1, Tsukuba, Ibaraki 305-8571, Japan.
出版信息
Inorg Chem. 2014 May 5;53(9):4272-4. doi: 10.1021/ic5002418. Epub 2014 Apr 17.
The one-dimensional complex [Mn(III)2Cu(II)(μ3-O)(Cl-sao)3(EtOH)2]·EtOH (Mn2Cu) was obtained by the metal replacement reaction of the trinuclear manganese complex (Et3NH)[Mn(III)3(μ3-O)Cl2(Cl-sao)3(MeOH)2(H2O)2] with [Cu(acac)2]. The Mn2Cu chain exhibits single-chain-magnet behavior with finite-size effects due to its large magnetic anisotropy.
一维配合物[Mn(III)2Cu(II)(μ3 - O)(Cl - sao)3(EtOH)2]·EtOH (Mn2Cu)是通过三核锰配合物(Et3NH)[Mn(III)3(μ3 - O)Cl2(Cl - sao)3(MeOH)2(H2O)2]与[Cu(acac)2]的金属置换反应得到的。由于其较大的磁各向异性，Mn2Cu链表现出具有有限尺寸效应的单链磁体行为。
Zotero 插件