Ide Yusuke, Sadakane Masahiro, Sano Tsuneji, Ogawa Makoto
J Nanosci Nanotechnol. 2014 Mar;14(3):2135-47. doi: 10.1166/jnn.2014.8525.
This review article describes the synthesis, modification, and function of lepidocrocite-type layered titanate (A(x)Ti(2-y)M(y)O4, A: A, interlayer cation; M, metal or vacancy). Due to the compositional variation, which affects cation exchange, semiconducting and swelling properties, lepidocrocite-type layered titanates have attracted increasing attention in solid-state materials chemistry. The immobilization of functional units has been done to improve the properties as well as to impart additional functions. Here, we highlight recent developments of hybrid materials derived from the intercalation of inorganic and organic cations, organic functional groups, and nanoparticles into lepidocrocite-type layered titanates.
这篇综述文章描述了纤铁矿型层状钛酸盐（A(x)Ti(2 - y)M(y)O4，A：层间阳离子；M：金属或空位）的合成、改性及功能。由于成分变化会影响阳离子交换、半导体和膨胀性能，纤铁矿型层状钛酸盐在固态材料化学领域已引起越来越多的关注。为了改善性能并赋予额外功能，已对功能单元进行了固定化处理。在此，我们重点介绍了通过将无机和有机阳离子、有机官能团及纳米颗粒插入纤铁矿型层状钛酸盐中而得到的杂化材料的最新进展。
