Department of Chemistry and Material Engineering, Faculty of Engineering, Shinshu University, Wakasato 4-17-1, Nagano 380-8553, Japan.
Chem Asian J. 2012 Sep;7(9):1980-92. doi: 10.1002/asia.201101015. Epub 2012 May 21.
The application of layered solids for molecular recognition is summarized. By using layered solids (silicates, aluminosilicates, titanates, hydroxides, and so on), ions and molecules can be concentrated from aqueous and vapor phases. The large surface area and tunable surface properties derived from the layered structures contribute to molecular recognition. The choice of materials and modification of the nanostructure were carefully investigated to optimize the performance based on molecular recognition (selective adsorption, substrate selective reaction, detection, etc.). The progress made in materials syntheses (variation of layered materials, sophisticated modification, controlled morphology, and processing) has made the design of materials more attractive and realistic.
层状固体在分子识别中的应用被总结。通过使用层状固体（硅酸盐、铝硅酸盐、钛酸盐、氢氧化物等），可以从水相和气相中浓缩离子和分子。层状结构衍生的大表面积和可调表面性质有助于分子识别。对材料的选择和纳米结构的修饰进行了仔细的研究，以基于分子识别（选择性吸附、底物选择性反应、检测等）优化性能。在材料合成方面的进展（层状材料的变化、精细的修饰、可控的形态和加工）使得材料设计更具吸引力和现实性。
