Massasso Giovanni, Long Jérôme, Haines Julien, Devautour-Vinot Sabine, Maurin Guillaume, Grandjean Agnès, Onida Barbara, Donnadieu Bruno, Larionova Joulia, Guérin Christian, Guari Yannick
Institut Charles Gerhardt Montpellier, UMR 5253, CNRS-UM2-ENSCM-UM1, Université Montpellier II , Place E. Bataillon, 34095 Montpellier, France.
Inorg Chem. 2014 May 5;53(9):4269-71. doi: 10.1021/ic500048z. Epub 2014 Apr 21.
The thermally stable Hofmann-type clathrate framework Ni(II)(pz)[Ni(II)(CN)4] (pz = pyrazine) was investigated for the efficient and reversible sorption of iodine (I2) in the gaseous phase and in solution with a maximum adsorption capacity of 1 mol of I2 per 1 mol of Ni(II)(pz)[Ni(II)(CN)4] in solution.
研究了热稳定的霍夫曼型包合物骨架Ni(II)(pz)[Ni(II)(CN)4]（pz = 吡嗪）在气相和溶液中对碘（I2）的高效可逆吸附，在溶液中每1摩尔Ni(II)(pz)[Ni(II)(CN)4]的最大吸附容量为1摩尔I2。
