Asymmetric dinuclear bis(dipyrrinato)zinc(II) complexes: broad absorption and unidirectional quantitative exciton transmission.

作者信息

Tsuchiya Mizuho, Sakamoto Ryota, Kusaka Shinpei, Kitagawa Yasutaka, Okumura Mitsutaka, Nishihara Hiroshi

机构信息

Department of Chemistry, Graduate School of Science, The University of Tokyo, 7-3-1, Hongo, Bunkyo-ku, Tokyo 113-0033, Japan.

出版信息

Chem Commun (Camb). 2014 Jun 4;50(44):5881-3. doi: 10.1039/c4cc01573h.

Asymmetric, heteroleptic dinuclear bis(dipyrrinato)zinc(II) complexes were synthesized and demonstrated to collect a wide range of light across the UV and visible regions (340-655 nm). The complexes also conveyed excitons across their structure from one end to the other, with spectroscopic studies demonstrating quantitative and fast energy transfer.