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6,7-二甲氧基-2,4-二苯基喹啉。

6,7-Dimeth-oxy-2,4-di-phenyl-quinoline.

作者信息

Prabhuswamy M, Madan Kumar S, Swaroop T R, Rangappa K S, Lokanath N K

机构信息

Department of Studies in Physics, Manasagangotri, University of Mysore, Mysore 570 006, India.

Department of Studies in Chemistry, Manasagangotri, University of Mysore, Mysore 570 006, India.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2014 Jan 18;70(Pt 2):o165. doi: 10.1107/S1600536814000725. eCollection 2014 Feb 1.

DOI:10.1107/S1600536814000725
PMID:24764883
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3998322/
Abstract

In the title structure of the title compound, C23H19NO2, two conformationally similar mol-ecules (A and B) comprise the asymmetric unit. The dihedral angle between phenyl rings bridged by the quinoline moiety are 76.25 (8)° in mol-ecule A and 70.39 (9)° in mol-ecule B. In the crystal, the independent mol-ecules are connected by C-H⋯O hydrogen bonds and the resulting dimeric aggregates are linked by π-π [inter-centroid distance = 3.7370 (8) Å] and C-H⋯π inter-actions, forming a three-dimensional architecture.

摘要

在标题化合物C23H19NO2的晶体结构中,两个构象相似的分子(A和B)构成不对称单元。喹啉部分桥连的苯环之间的二面角在分子A中为76.25 (8)°,在分子B中为70.39 (9)°。在晶体中,独立分子通过C-H⋯O氢键相连,形成的二聚体聚集体通过π-π[质心间距 = 3.7370 (8) Å]和C-H⋯π相互作用相连,形成三维结构。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5bb9/3998322/f53f23c07148/e-70-0o165-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5bb9/3998322/cc27a49667ea/e-70-0o165-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5bb9/3998322/f53f23c07148/e-70-0o165-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5bb9/3998322/cc27a49667ea/e-70-0o165-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5bb9/3998322/f53f23c07148/e-70-0o165-fig2.jpg

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本文引用的文献

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