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[二（2,6 - 二乙基 - 4 - 苯基苯基）丁烷 - 2,3 - 二亚胺 - κ(2) N,N']二溴化镍（II）

[N,N'-Bis(2,6-diethyl-4-phenyl-phen-yl)butane-2,3-di-imine-κ(2) N,N']di-bromido-nickel(II).

作者信息

Yuan Jianchao, Xia Jingjing, Xu Weibing, Mu Yanqiong

机构信息

Key Laboratory of Eco-Environment-Related Polymer Materials of Ministry of, Education, Key Laboratory of Polymer Materials of Gansu Province, College of Chemistry & Chemical Engineering, Northwest Normal University, Lanzhou 730070, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2014 Feb 15;70(Pt 3):m102. doi: 10.1107/S160053681400292X. eCollection 2014 Mar 1.

DOI:10.1107/S160053681400292X
PMID:24764936
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3998469/
Abstract

The complex molecule in the title compound, [NiBr2(C36H40N2)], has mirror symmetry. The Ni(II) atom and two Br atoms are located on the mirror plane. The Ni(II) atom is four-coordinated by the two Br atoms and two N atoms from an N,N'-bis(2,6-diethyl-4-phenyl-phen-yl)butane-2,3-di-imine ligand in a distorted tetra-hedral geometry. The dihedral angle formed between the two adjacent benzene rings is 47.1 (1)°.

摘要

标题化合物[NiBr₂(C₃₆H₄₀N₂)]中的复杂分子具有镜像对称性。Ni(II)原子和两个Br原子位于镜面上。Ni(II)原子由两个Br原子和来自N,N'-双(2,6-二乙基-4-苯基苯基)丁烷-2,3-二亚胺配体的两个N原子以扭曲的四面体几何构型进行四配位。两个相邻苯环之间形成的二面角为47.1 (1)°。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7226/3998469/e0868f5f69df/e-70-0m102-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7226/3998469/e0868f5f69df/e-70-0m102-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7226/3998469/e0868f5f69df/e-70-0m102-fig1.jpg

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